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Makale Tam Makale Uluslararası 2025

Electrochemical Detection of Melatonin in the Presence of Dopamine on a Ce-Doped Poly(bromocresol purple)-Modified Electrode

Hülya Öztürk Doğan, Neslihan Çelebi, Arzu Kavaz Yüksel

ACS OMEGA Cilt 10 · Sayı 41 · ss. 48091–48099 · 09.10.2025
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Özet

In this study, bromocresol purple was electropolymerized on the surface of a pencil graphite electrode (PGE) and electrochemically doped with cerium (Ce) nanoparticles. The Ce-doped poly(bromocresol purple) (Ce/PBCP)-modified PGE was characterized using energy dispersive X-ray spectroscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy. The prepared Ce/PBCP electrode was investigated for the electrochemical determination of melatonin in the presence of dopamine. The electrochemical activity of the Ce/PBCP electrode was compared with that of undoped PBCP, Ce/PGE, and bare PGE. The peak potential and peak current for melatonin oxidation were +800 mV and 820 mu A cm-2, respectively. The detection limit of melatonin was 0.038 mu M, and the Ce/PBCP electrode exhibited high activity in the presence of interfering species. In addition, the use of a Ce/PBCP electrode for detecting melatonin in a terebinth sample, a real food sample, was also investigated, and the produced electrode demonstrated high performance.

Atıf için künye

Öztürk Doğan, H., Çelebi, N., & Kavaz Yüksel, A. (2025). Electrochemical Detection of Melatonin in the Presence of Dopamine on a Ce-Doped Poly(bromocresol purple)-Modified Electrode. ACS OMEGA, 10(41), 48091–48099. https://doi.org/10.1021/acsomega.5c04226

BibTeX
@article{ozturkdogan2025-331673,
  author = {Öztürk Doğan, Hülya and Çelebi, Neslihan and Kavaz Yüksel, Arzu},
  title = {Electrochemical Detection of Melatonin in the Presence of Dopamine on a Ce-Doped Poly(bromocresol purple)-Modified Electrode},
  journal = {ACS OMEGA},
  year = {2025},
  volume = {10},
  number = {41},
  pages = {48091--48099},
  issn = {2470-1343},
  doi = {10.1021/acsomega.5c04226},
  url = {https://akademik.atauni.edu.tr/yayinlar/331673-electrochemical-detection-of-melatonin-in-the-presence-of-dopamine-on-a-ce-doped}
}