Atatürk Üniversitesi Atatürk Üniversitesi
Ara
Yayınlara dön
Makale Tam Makale Uluslararası 2023

Two-step novel aromatic polyimide synthesis and characterization: Survey of energy calculations and diode applications

Ahmet Çağrı Ata, Ümit Yildiko, Aslihan Aycan Tanriverdi, Rüstem Ebiri, Evin Yiğit, İkram Orak, İsmail Cakmak

JOURNAL OF APPLIED POLYMER SCIENCE Cilt 140 · Sayı 14 · 10.04.2023
DOI ile aç

Özet

© 2023 Wiley Periodicals LLC.Herein, aromatic polyimides (API) synthesis was carried out by polycondensation of the original diamine (new synthesis) and commercial dianhydride. The original diamine and API were characterized by different analysis techniques. In addition, experimental and quantum chemical calculations of the synthesized API were analyzed by density functional theory method. Quantum theory analysis of atoms in molecules was performed for a structural unit of the compound. Here, the proton transfer phenomenon was investigated. The main purpose of synthesizing API1 was diode application. Therefore, the Au/API-p-Si/Al diode was produced accomplishedly. When the electrical characterization of the obtained diode structure was made, electrical parameter values such as ideality factor (n) (between 1.9 and 3.8), barrier height (ΦB) (0.73–0.28 eV), and series resistance (Rs) (1270–40,187 kΩ) were calculated.

Anahtar kelimeler

FT-IR MEMBRANES DFT Electrical properties Interface states VOLTAGE MOLECULAR-STRUCTURE HOMO-LUMO aromatic polyimide diode application QTAIM analysis H-1-NMR MEP

Atıf için künye

Ata, A. Ç., Yildiko, Ü., Tanriverdi, A. A., Ebiri, R., Yiğit, E., Orak, İ., & Cakmak, İ. (2023). Two-step novel aromatic polyimide synthesis and characterization: Survey of energy calculations and diode applications. JOURNAL OF APPLIED POLYMER SCIENCE, 140(14). https://doi.org/10.1002/app.53689

BibTeX
@article{ata2023-80916,
  author = {Ata, Ahmet Çağrı and Yildiko, Ümit and Tanriverdi, Aslihan Aycan and Ebiri, Rüstem and Yiğit, Evin and Orak, İkram and Cakmak, İsmail},
  title = {Two-step novel aromatic polyimide synthesis and characterization: Survey of energy calculations and diode applications},
  journal = {JOURNAL OF APPLIED POLYMER SCIENCE},
  year = {2023},
  volume = {140},
  number = {14},
  issn = {0021-8995},
  doi = {10.1002/app.53689},
  url = {https://akademik.atauni.edu.tr/yayinlar/80916-two-step-novel-aromatic-polyimide-synthesis-and-characterization-survey-of}
}