Novel pyrene-BODIPY dyes based on cyclotriphosphazene scaffolds: Synthesis, photophysical and spectroelectrochemical properties
Özet
Two novel cyclotriphosphazene compounds (Cpz-2, 3) bearing mono- and distyryl(pyrene) borondipyrromethene (BODIPY) dyes (Bod-4, 5) were synthesized and characterized by using elemental analysis, FT-IR, MALDI-TOF, H-1 NMR, C-13 NMR and (3)1P NMR techniques. The photophysical properties of these novel compounds were investigated by UV-Vis, fluorescence spectroscopy, and electrochemical properties were investigated by CV and SWV measurements. Subsequently, electrochromic properties of novel cyclotriphosphazene compounds (Cpz-2, 3) and their precursor dyes (Bod-4, 5) were investigated via in-situ spectroelectrochemical measurements. According to results, they gave electrochemically manufactured types having various colors in their diverse oxidation states in solution, suggesting that they may have a significant role in development of the color exchange matter in electrochromic device technologies.
Sürdürülebilir Kalkınma Amaçları
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SKA 3: Sağlıklı Bireyler
Atıf için künye
Cetindere, S., Tümay, S. O., Senocak, A., Kilic, A., DURMUŞ, M., Demirbas, E., & Yesilot, S. (2019). Novel pyrene-BODIPY dyes based on cyclotriphosphazene scaffolds: Synthesis, photophysical and spectroelectrochemical properties. Inorganica Chimica Acta, 494, 132–140. https://doi.org/10.1016/j.ica.2019.05.022
BibTeX
@article{cetindere2019-80593,
author = {Cetindere, Seda and Tümay, Süreyya Oğuz and Senocak, Ahmet and Kilic, Adem and DURMUŞ, MAHMUT and Demirbas, Erhan and Yesilot, Serkan},
title = {Novel pyrene-BODIPY dyes based on cyclotriphosphazene scaffolds: Synthesis, photophysical and spectroelectrochemical properties},
journal = {Inorganica Chimica Acta},
year = {2019},
volume = {494},
pages = {132--140},
issn = {0020-1693},
doi = {10.1016/j.ica.2019.05.022},
url = {https://akademik.atauni.edu.tr/yayinlar/80593-novel-pyrene-bodipy-dyes-based-on-cyclotriphosphazene-scaffolds-synthesis}
}