New cyclotriphosphazene ligand containing imidazole rings and its one-dimensional copper(II) coordination polymer
Özet
An imidazole and biphenyl-appended cyclotriphosphazene (2, L) and its 1D copper(II) coordination polymer (3) which formulated as [L-2(CuCl2)](n) were synthesized. The structure of 2 was determined by elemental analysis and different spectroscopic tecqniques. The crystal structures of 2 and 3 were defined by single-crystal X-ray crystallography. The copper atom in complex 3 was in a slightly distorted octahedral geometry which coordinated by four monodentate imidazole nitrogen and two chlorine atoms. The magnetic properties of 3 was discussed via ESR spectroscopy. The thermal properties of 2 and 3 were investigated by thermogravimetric analysis (TGA). The photophysical and electrochemical properties of 2 and 3 were evaluated by UV-Vis-fluorescence spectroscopies and cyclic (CV)-square wave (SWV) voltammetric techniques. In addition, HOMO-LUMO energy levels were calculated according to UV-Vis absorption and CV measurements. (C) 2020 Elsevier B.V. All rights reserved.
Sürdürülebilir Kalkınma Amaçları
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SKA 2: Açlığa Son
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SKA 3: Sağlıklı Bireyler
Atıf için künye
Ibisoglu, H., Atilla, D., Tümay, S. O., Senocak, A., Duygulu, E., & Yuksel, F. (2020). New cyclotriphosphazene ligand containing imidazole rings and its one-dimensional copper(II) coordination polymer. Journal of Molecular Structure, 1208. https://doi.org/10.1016/j.molstruc.2020.127888
BibTeX
@article{ibisoglu2020-80574,
author = {Ibisoglu, Hanife and Atilla, Devrim and Tümay, Süreyya Oğuz and Senocak, Ahmet and Duygulu, Ercan and Yuksel, Fatma},
title = {New cyclotriphosphazene ligand containing imidazole rings and its one-dimensional copper(II) coordination polymer},
journal = {Journal of Molecular Structure},
year = {2020},
volume = {1208},
issn = {0022-2860},
doi = {10.1016/j.molstruc.2020.127888},
url = {https://akademik.atauni.edu.tr/yayinlar/80574-new-cyclotriphosphazene-ligand-containing-imidazole-rings-and-its-one}
}