Investigation of potential hybrid capacitor property of chelated N-Heterocyclic carbene Ruthenium(II) complex

Akkoc, Mitat; Öz, Erdinç; Demirel, Serkan; Dorcet, Vincent; Roisnel, Thierry; BAYRİ, ALİ; Bruneau, Christian; ALTIN, SERDAR; YAŞAR, SEDAT; ÖZDEMİR, İSMAİL

doi:10.1016/j.jorganchem.2018.04.035

Makale Tam Makale Uluslararası 2018 Açık erişimli

Investigation of potential hybrid capacitor property of chelated N-Heterocyclic carbene Ruthenium(II) complex

Mitat Akkoc, Erdinç Öz, Serkan Demirel, Vincent Dorcet, Thierry Roisnel, ALİ BAYRİ, Christian Bruneau, SERDAR ALTIN, SEDAT YAŞAR, İSMAİL ÖZDEMİR

JOURNAL OF ORGANOMETALLIC CHEMISTRY Cilt 866 · ss. 214–222 · 01.07.2018

DOI ile aç

Özet

The synthesis of chelated ruthenium(II) complex type Ru(eta(6)-HMB) (NHC) Cl (NHC = N-heterocyclic carbene, HMB = hexamethylbenzene) is presented. The ruthenium(II)-NHC complex 6 was obtained in good yield and was fully characterised by NMR spectroscopy, X-ray diffraction and HRMS analysis. Electrochemical analysis by cyclic voltammetry (CV) revealed reversible redox behaviour at the ruthenium centre in 6. DFT studies and the catalytic activity of complex 6 on transfer hydrogenation reaction of aryl ketones are also presented. The potential hybrid capacitor applications of Ru-NHC complex is discussed and reported firstly in the literature. It was found that the highest performance was found at 20.1 F/g, which is a promising result for energy storage applications. (c) 2018 Elsevier B.V. All rights reserved.

Anahtar kelimeler

CHEMISTRY transfer hydrogenation CARBON COORDINATION LIGANDS Supercapacitors N-heterocyclic carbene BEARING Cyclic voltametry of ruthenium(II) Hybrid capasitor Ruthenium Chelate ligand CATALYTIC-ACTIVITIES H ACTIVATION C-H

Atıf için künye

Akkoc, M., Öz, E., Demirel, S., Dorcet, V., Roisnel, T., BAYRİ, A., Bruneau, C., ALTIN, S., YAŞAR, S., & ÖZDEMİR, İ. (2018). Investigation of potential hybrid capacitor property of chelated N-Heterocyclic carbene Ruthenium(II) complex. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 866, 214–222. https://doi.org/10.1016/j.jorganchem.2018.04.035

BibTeX

@article{akkoc2018-80057,
  author = {Akkoc, Mitat and Öz, Erdinç and Demirel, Serkan and Dorcet, Vincent and Roisnel, Thierry and BAYRİ, ALİ and Bruneau, Christian and ALTIN, SERDAR and YAŞAR, SEDAT and ÖZDEMİR, İSMAİL},
  title = {Investigation of potential hybrid capacitor property of chelated N-Heterocyclic carbene Ruthenium(II) complex},
  journal = {JOURNAL OF ORGANOMETALLIC CHEMISTRY},
  year = {2018},
  volume = {866},
  pages = {214--222},
  issn = {0022-328X},
  doi = {10.1016/j.jorganchem.2018.04.035},
  url = {https://akademik.atauni.edu.tr/yayinlar/80057-investigation-of-potential-hybrid-capacitor-property-of-chelated-n-heterocyclic}
}