Novel fully-BODIPY functionalized cyclotetraphosphazene photosensitizers having high singlet oxygen quantum yields
Özet
Novel fully-BODIPY functionalized dendrimeric cyclotetraphosphazenes (FBCP 1 and 2) have been synthesized and characterized by H-1, C-13 and P-31 NMR spectroscopies. The photophysical and photochemical properties of FBCP 1 and 2 are investigated in dichloromethane solution. The effectiveness of singlet oxygen generation was measured for FBCP 1 and 2 by UV-Vis spectra monitoring of the solution of 1,3-diphenylisobenzofuran (DPBF), which is, a well-known trapping molecule used in detection of singlet oxygen. FBCP 1 and 2 show high molar extinction coefficients in the NIR region, good singlet oxygen quantum yields and appropriate photo degradation. The data presented in the work indicate that the dendrimeric cyclotetraphosphazenes are effective singlet oxygen photosensitizers that might be used for various areas of applications such as photodynamic therapy and photocatalysis. (C) 2017 Elsevier B.V. All rights reserved.
Anahtar kelimeler
Atıf için künye
Şenkuytu, E., & Tanrıverdi Eçik, E. (2017). Novel fully-BODIPY functionalized cyclotetraphosphazene photosensitizers having high singlet oxygen quantum yields. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 182, 26–31. https://doi.org/10.1016/j.saa.2017.03.065
BibTeX
@article{senkuytu2017-78474,
author = {Şenkuytu, Elif and Tanrıverdi Eçik, Esra},
title = {Novel fully-BODIPY functionalized cyclotetraphosphazene photosensitizers having high singlet oxygen quantum yields},
journal = {Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy},
year = {2017},
volume = {182},
pages = {26--31},
issn = {1386-1425},
doi = {10.1016/j.saa.2017.03.065},
url = {https://akademik.atauni.edu.tr/yayinlar/78474-novel-fully-bodipy-functionalized-cyclotetraphosphazene-photosensitizers-having}
}