Nucleophilic substitution reactions of monofunctional nucleophilic reagents with cyclotriphosphazenes containing 2,2-dioxybiphenyl units
Özet
The nucleophilic substitution reactions of mono- and bis-spiro-2,2'-dioxybiphenyl cyclotriphosphazenes (3 and 4) with cyclopropanemethylamine (5) and aniline (6) were performed in the presence of trimethylamine in THF. Five novel cyclopropanemethylamino- and anilino-substituted spiro-2,2'-dioxybiphenyl cyclotriphosphazene derivatives (7-11) were obtained from these reactions. The molecular structures of the new cyclotriphosphazene derivatives (7-11) were characterized by elemental analysis, MALDI-TOF MS, FT-IR, and NMR (P-31 and H-1) spectroscopies. The structure of the spiro-(2,2'-dioxybiphenyl)-bis-(anilino)-cyclotriphosphazene (11) was also determined by single-crystal X-ray crystallography.
Atıf için künye
Tanrıverdi Eçik, E., İBİŞOĞLU, H., YENİLMEZ ÇİFTÇİ, G., Demir, G., Erdemir, E., & YÜKSEL, F. (2020). Nucleophilic substitution reactions of monofunctional nucleophilic reagents with cyclotriphosphazenes containing 2,2-dioxybiphenyl units. TURKISH JOURNAL OF CHEMISTRY, 44(1), 87–109. https://doi.org/10.3906/kim-1907-45
BibTeX
@article{tanriverdiecik2020-78454,
author = {Tanrıverdi Eçik, Esra and İBİŞOĞLU, HANİFE and YENİLMEZ ÇİFTÇİ, GÖNÜL and Demir, Gizem and Erdemir, Eda and YÜKSEL, FATMA},
title = {Nucleophilic substitution reactions of monofunctional nucleophilic reagents with cyclotriphosphazenes containing 2,2-dioxybiphenyl units},
journal = {TURKISH JOURNAL OF CHEMISTRY},
year = {2020},
volume = {44},
number = {1},
pages = {87--109},
issn = {1300-0527},
doi = {10.3906/kim-1907-45},
url = {https://akademik.atauni.edu.tr/yayinlar/78454-nucleophilic-substitution-reactions-of-monofunctional-nucleophilic-reagents-with}
}