Structural properties of new spiro-1,3-propanediaminocyclotriphosphazene derivatives
Özet
New 1,3-propanediaminocyclotriphosphazene derivatives (7-17) were synthesized from the reactions of spiro-1,3-propanediaminocyclotriphosphazene, N3P3Cl4[NH(CH2)(3)NH] (1) with the cyclopropanemethylamine (2), cyclohexylamine (3), pyrrolidine (4) cyclohexanol (5), cyclopropylmethanol (6). The structures of the novel compounds (7-17) were characterized by elemental analysis, mass spectrometry, H-1 and P-31 NMR spectroscopy. The molecular structures of 8, 12 and 13 were determined by X-ray crystallography. The structures of all these three compounds are in the monoclinic crystal system; compounds 8 and 12 have the P21/c space group while compound 13 has the P21/n space group. The ring conformation of the cyclotriphosphazene and other external rings were investigated based on the X-ray crystal structures. (C) 2011 Elsevier Ltd. All rights reserved.
Anahtar kelimeler
Atıf için künye
YENİLMEZ ÇİFTÇİ, G., Şenkuytu, E., Tanrıverdi Eçik, E., KILIÇ, A., & YÜKSEL, F. (2011). Structural properties of new spiro-1,3-propanediaminocyclotriphosphazene derivatives. POLYHEDRON, 30(13), 2227–2236. https://doi.org/10.1016/j.poly.2011.05.041
BibTeX
@article{yenilmezciftci2011-78445,
author = {YENİLMEZ ÇİFTÇİ, GÖNÜL and Şenkuytu, Elif and Tanrıverdi Eçik, Esra and KILIÇ, ADEM and YÜKSEL, FATMA},
title = {Structural properties of new spiro-1,3-propanediaminocyclotriphosphazene derivatives},
journal = {POLYHEDRON},
year = {2011},
volume = {30},
number = {13},
pages = {2227--2236},
issn = {0277-5387},
doi = {10.1016/j.poly.2011.05.041},
url = {https://akademik.atauni.edu.tr/yayinlar/78445-structural-properties-of-new-spiro-13-propanediaminocyclotriphosphazene}
}