Synthesis of diols using the hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate)

Çelik, Murat; ALP, Cemalettin; COSKUN, Betul; Gultekin, M. Serdar; BALCI, Metin

doi:10.1016/j.tetlet.2006.03.137

Makale Tam Makale Uluslararası 2006

Synthesis of diols using the hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate)

Murat Çelik, Cemalettin ALP, Betul COSKUN, M. Serdar Gultekin, Metin BALCI

Tetrahedron Letters Cilt 47 · Sayı 22 · ss. 3659–3663 · 29.05.2006

DOI ile aç

Özet

1.2- and 1.3-Bis(trifluoroacetoxy) alcohols are easily obtained from the one-pot reaction of alkenes with phenyliodine(III) bis(trifluoroacetate) (PIFA) in the absence of any additive or catalyst. The products were converted into the corresponding diols by ammonolysis. The use of bicyclic alkenes has shown that rearranged 1,3-diacetoxy alcohols are mostly formed as the major products. (c) 2006 Elsevier Ltd. All rights reserved.

Anahtar kelimeler

oxidation benzonorbornadiene HIGH-TEMPERATURE BROMINATION Rearrangement phenyliodine(III) bis(trifluoroacetate) PIFA 1.2-diols 1.3-diols CIS

Atıf için künye

Çelik, M., ALP, C., COSKUN, B., Gultekin, M. S., & BALCI, M. (2006). Synthesis of diols using the hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate). Tetrahedron Letters, 47(22), 3659–3663. https://doi.org/10.1016/j.tetlet.2006.03.137

BibTeX

@article{celik2006-71787,
  author = {Çelik, Murat and ALP, Cemalettin and COSKUN, Betul and Gultekin, M. Serdar and BALCI, Metin},
  title = {Synthesis of diols using the hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate)},
  journal = {Tetrahedron Letters},
  year = {2006},
  volume = {47},
  number = {22},
  pages = {3659--3663},
  issn = {0040-4039},
  doi = {10.1016/j.tetlet.2006.03.137},
  url = {https://akademik.atauni.edu.tr/yayinlar/71787-synthesis-of-diols-using-the-hypervalent-iodineiii-reagent-phenyliodineiii}
}