Total Syntheses of Multicaulins via Oxidative Photocyclization of Stilbenes

SECINTI, Hatice; Burmaoğlu, Serdar; Altundas, Ramazan; Seçen, Hasan

doi:10.1021/np5001158

Makale Tam Makale Uluslararası 2014

Total Syntheses of Multicaulins via Oxidative Photocyclization of Stilbenes

Hatice SECINTI, Serdar Burmaoğlu, Ramazan Altundas, Hasan Seçen

JOURNAL OF NATURAL PRODUCTS Cilt 77 · Sayı 9 · ss. 2134–2137 · 01.09.2014

DOI ile aç

Özet

The Wittig reaction of 3-isopropyl-4-methoxybenzaldehyde and 2,3-dimethylbenzylphosphonium bromide afforded the corresponding stilbene mixture 16. Oxidative photocyclization of stilbene 16 with iodine facilitated the first total synthesis of 7-isopropyl-6-methoxy-1,2-dimethylphenanthrene, multicaulin (1). The O-demethylation of 1 with BBr3 afforded the 7-isopropyl-1,2-dimethylphenanthren-6-ol, O-demethylmulticaulin (2).

Atıf için künye

SECINTI, H., Burmaoğlu, S., Altundas, R., & Seçen, H. (2014). Total Syntheses of Multicaulins via Oxidative Photocyclization of Stilbenes. JOURNAL OF NATURAL PRODUCTS, 77(9), 2134–2137. https://doi.org/10.1021/np5001158

BibTeX

@article{secinti2014-71425,
  author = {SECINTI, Hatice and Burmaoğlu, Serdar and Altundas, Ramazan and Seçen, Hasan},
  title = {Total Syntheses of Multicaulins via Oxidative Photocyclization of Stilbenes},
  journal = {JOURNAL OF NATURAL PRODUCTS},
  year = {2014},
  volume = {77},
  number = {9},
  pages = {2134--2137},
  issn = {0163-3864},
  doi = {10.1021/np5001158},
  url = {https://akademik.atauni.edu.tr/yayinlar/71425-total-syntheses-of-multicaulins-via-oxidative-photocyclization-of-stilbenes}
}