Synthesis of two alnustone-like natural diarylheptanoids via 4+3 strategy
Özet
The first total synthesis of (4E,6E)-1,7-bis(3,4-dihydroxyphenyl)-hepta-4,6-dien-3-one and an alternative synthesis of (4E,6E)-1,7-bis(4-hydroxyphenyl)-hepta-4,6-dien-3-one, two natural diarylheptanoids, mainly based on Claisen-Schmidt condensation were described. The crucial steps of the syntheses were the condensation of OH-protected 4-aryl-2-butanones with OH-protected 3-aryl-acrylaldehydes by the in situ enamination and then deprotection of OH groups to give the corresponding natural diarylheptanoids.
Atıf için künye
Burmaoğlu, S., CELIK, H., Göksu, S., Maraş, A., Altundas, R., & Seçen, H. (2009). Synthesis of two alnustone-like natural diarylheptanoids via 4+3 strategy. SYNTHETIC COMMUNICATIONS, 39(9), 1549–1562. https://doi.org/10.1080/00397910802542036
BibTeX
@article{burmaoglu2009-71422,
author = {Burmaoğlu, Serdar and CELIK, Huelya and Göksu, Süleyman and Maraş, Ahmet and Altundas, Ramazan and Seçen, Hasan},
title = {Synthesis of two alnustone-like natural diarylheptanoids via 4+3 strategy},
journal = {SYNTHETIC COMMUNICATIONS},
year = {2009},
volume = {39},
number = {9},
pages = {1549--1562},
issn = {0039-7911},
doi = {10.1080/00397910802542036},
url = {https://akademik.atauni.edu.tr/yayinlar/71422-synthesis-of-two-alnustone-like-natural-diarylheptanoids-via-43-strategy}
}