A NOVEL SYNTHESIS OF CONDURITOL-C AND CONDURITOL-E VIA P-BENZOQUINONE

Seçen, Hasan; Maraş, Ahmet; SUTBEYAZ, Yaşar; BALCI, M

doi:10.1080/00397919208021660

Makale Tam Makale Uluslararası 1992

A NOVEL SYNTHESIS OF CONDURITOL-C AND CONDURITOL-E VIA P-BENZOQUINONE

Hasan Seçen, Ahmet Maraş, Yaşar SUTBEYAZ, M BALCI

SYNTHETIC COMMUNICATIONS Cilt 22 · Sayı 18 · ss. 2613–2619 · 01.01.1992

DOI ile aç

Özet

A new and stereospecific synthesis for Conduritol-C 8 and Conduritol-E 13a has been developed starting from p-benzoquinone 1. 1,4-oxygen functionalities were introduced in both synthesis by the reduction of dibromo p-benzoquinone 2 with NaBH4. 2,3-oxygen functionalities were introduced by KMnO4 oxidation of 4 for Conduritol C 8. Oxidation of 3 with m-chloroperbenzoic acid gave 9. Acid-catalyzed ring opening reaction of 9 gave 10a which leads to Conduritol-E.

Atıf için künye

Seçen, H., Maraş, A., SUTBEYAZ, Y., & BALCI, M. (1992). A NOVEL SYNTHESIS OF CONDURITOL-C AND CONDURITOL-E VIA P-BENZOQUINONE. SYNTHETIC COMMUNICATIONS, 22(18), 2613–2619. https://doi.org/10.1080/00397919208021660

BibTeX

@article{secen1992-71377,
  author = {Seçen, Hasan and Maraş, Ahmet and SUTBEYAZ, Yaşar and BALCI, M},
  title = {A NOVEL SYNTHESIS OF CONDURITOL-C AND CONDURITOL-E VIA P-BENZOQUINONE},
  journal = {SYNTHETIC COMMUNICATIONS},
  year = {1992},
  volume = {22},
  number = {18},
  pages = {2613--2619},
  issn = {0039-7911},
  doi = {10.1080/00397919208021660},
  url = {https://akademik.atauni.edu.tr/yayinlar/71377-a-novel-synthesis-of-conduritol-c-and-conduritol-e-via-p-benzoquinone}
}