AN EFFICIENT AND STEREOSPECIFIC SYNTHESIS OF PROTO-QUERCITOL

Seçen, Hasan; Salamcı, Emine; SUTBEYAZ, Yaşar; BALCI, M

doi:10.1055/s-1993-22550

Makale Tam Makale Uluslararası 1993

AN EFFICIENT AND STEREOSPECIFIC SYNTHESIS OF PROTO-QUERCITOL

Hasan Seçen, Emine Salamcı, Yaşar SUTBEYAZ, M BALCI

Synlett Sayı 8 · ss. 609–610 · 01.08.1993

DOI ile aç

Özet

A new and stereospecific synthesis for DL-proto-quercitol has beeR developed starting from commercial 1,4-cyclohexadiene. Photooxygenation of 1 resulted in the formation of 3 whose configuration has been determined from spectroscopic data and by chemical interconversions. LiAlH4 or thiourea reduction of the peroxide linkages in 3 gave cyclohexenetriol 4a. KMnO4 oxidation of the corresponding cyclohexene acetate 4b followed by ammonolysis gave 6a as the sole product in high yield.

Atıf için künye

Seçen, H., Salamcı, E., SUTBEYAZ, Y., & BALCI, M. (1993). AN EFFICIENT AND STEREOSPECIFIC SYNTHESIS OF PROTO-QUERCITOL. Synlett(8), 609–610. https://doi.org/10.1055/s-1993-22550

BibTeX

@article{secen1993-71012,
  author = {Seçen, Hasan and Salamcı, Emine and SUTBEYAZ, Yaşar and BALCI, M},
  title = {AN EFFICIENT AND STEREOSPECIFIC SYNTHESIS OF PROTO-QUERCITOL},
  journal = {Synlett},
  year = {1993},
  number = {8},
  pages = {609--610},
  issn = {0936-5214},
  doi = {10.1055/s-1993-22550},
  url = {https://akademik.atauni.edu.tr/yayinlar/71012-an-efficient-and-stereospecific-synthesis-of-proto-quercitol}
}