Effective bromo and chloro peroxidation catalysed by tungsten(VI) amino triphenolate complexes
Özet
Amino triphenolate tungsten(VI) complexes have been prepared and they proved to be efficient catalysts in haloperoxidation reactions using hydrogen peroxide as a terminal oxidant and inorganic sources of halides. In particular, interesting results have been obtained in the challenging chloroperoxidation reactivity (catalyst loading down to 0.05% with TONs up to 900). A comparison among three different metal complexes bearing the same ligand (vanadium(V), molybdenum(VI) and tungsten(VI)) showed much better performances of the last complex both on bromo and chloro peroxidations.
Atıf için künye
BADETTI, E., ROMANO, F., MARCHIO, L., Taskesenlioglu, S., Daştan, A., ZONTA, C., & LICINI, G. (2016). Effective bromo and chloro peroxidation catalysed by tungsten(VI) amino triphenolate complexes. DALTON TRANSACTIONS, 45(37), 14603–14608. https://doi.org/10.1039/c6dt01780k
BibTeX
@article{badetti2016-70725,
author = {BADETTI, Elena and ROMANO, Francesco and MARCHIO, Luciano and Taskesenlioglu, Sara and Daştan, Arif and ZONTA, Cristiano and LICINI, Giulia},
title = {Effective bromo and chloro peroxidation catalysed by tungsten(VI) amino triphenolate complexes},
journal = {DALTON TRANSACTIONS},
year = {2016},
volume = {45},
number = {37},
pages = {14603--14608},
issn = {1477-9226},
doi = {10.1039/c6dt01780k},
url = {https://akademik.atauni.edu.tr/yayinlar/70725-effective-bromo-and-chloro-peroxidation-catalysed-by-tungstenvi-amino}
}