One-pothomo- andcross-couplingof diazanaphthalenes viaC-Hsubstitution: Synthesis of Bis- andTris-diazanaphthalenes
Özet
The transition metal-free coupling reactions of unactivated diazanaphthalenes were studied using only lithium tetramethylpiperidine (LiTMP) reagent. Symmetrical and nonsymmetrical bis-diazanaphthalenes were synthesized in moderate to high yield by homo- and cross-coupling of related monomers. In addition, the single-step synthesis of diquinoxalino [2,3-a: 2', 3'c] phenazine and 2,2': 3', 2 '' - terquinoxaline using the appropriate equivalent amount of LiTMP was performed. The products were characterized by means of NMR spectroscopy and HRMS spectrometry.
Atıf için künye
Uçar, S., & Daştan, A. (2020). One-pothomo- andcross-couplingof diazanaphthalenes viaC-Hsubstitution: Synthesis of Bis- andTris-diazanaphthalenes. Journal of Heterocyclic Chemistry, 57(11), 4013–4022. https://doi.org/10.1002/jhet.4111
BibTeX
@article{ucar2020-70707,
author = {Uçar, Sefa and Daştan, Arif},
title = {One-pothomo- andcross-couplingof diazanaphthalenes viaC-Hsubstitution: Synthesis of Bis- andTris-diazanaphthalenes},
journal = {Journal of Heterocyclic Chemistry},
year = {2020},
volume = {57},
number = {11},
pages = {4013--4022},
issn = {0022-152X},
doi = {10.1002/jhet.4111},
url = {https://akademik.atauni.edu.tr/yayinlar/70707-one-pothomo-andcross-couplingof-diazanaphthalenes-viac-hsubstitution-synthesis}
}