Cyclotrimerization of 'Oxabenzonorbornadiene': Synthesis of syn- and anti-5,6,11,12,17,18-hexahydro-5,18:6,11 : 12,17-triepoxytrinaphthylene

DE LUCCHI, O; Daştan, Arif; ALTUNDAS, A; FABRIS, F; BALCI, M

doi:10.1002/hlca.200490213

Makale Tam Makale Uluslararası 2004

Cyclotrimerization of 'Oxabenzonorbornadiene': Synthesis of syn- and anti-5,6,11,12,17,18-hexahydro-5,18:6,11 : 12,17-triepoxytrinaphthylene

O DE LUCCHI, Arif Daştan, A ALTUNDAS, F FABRIS, M BALCI

HELVETICA CHIMICA ACTA Cilt 87 · Sayı 9 · ss. 2364–2367 · 01.01.2004

DOI ile aç

Özet

An efficient synthetic route to the concave-shaped, potentially ionophoric syn- and anti-isomers of 5,6,11,12,17,18-hexahydro-5,18:6,11:12,17-triepoxytrinaphthylene (4) was elaborated. Starting from 'oxabenzonorbornadiene' (5), the stannylated precursor 9 was prepared in three steps, followed by cyclotrimerization ;catalyzed by copper(I) thiophene-2-carboxylate (CuTC), which afforded 4 in a synlanti ratio of 5:4.

Atıf için künye

DE LUCCHI, O., Daştan, A., ALTUNDAS, A., FABRIS, F., & BALCI, M. (2004). Cyclotrimerization of 'Oxabenzonorbornadiene': Synthesis of syn- and anti-5,6,11,12,17,18-hexahydro-5,18:6,11 : 12,17-triepoxytrinaphthylene. HELVETICA CHIMICA ACTA, 87(9), 2364–2367. https://doi.org/10.1002/hlca.200490213

BibTeX

@article{delucchi2004-70696,
  author = {DE LUCCHI, O and Daştan, Arif and ALTUNDAS, A and FABRIS, F and BALCI, M},
  title = {Cyclotrimerization of 'Oxabenzonorbornadiene': Synthesis of syn- and anti-5,6,11,12,17,18-hexahydro-5,18:6,11 : 12,17-triepoxytrinaphthylene},
  journal = {HELVETICA CHIMICA ACTA},
  year = {2004},
  volume = {87},
  number = {9},
  pages = {2364--2367},
  issn = {0018-019X},
  doi = {10.1002/hlca.200490213},
  url = {https://akademik.atauni.edu.tr/yayinlar/70696-cyclotrimerization-of-oxabenzonorbornadiene-synthesis-of-syn-and-anti-5611121718}
}