Cyclotrimerization of benzobarrelene: Synthesis of new isomeric barrelene architectures

Daştan, Arif; FABRIS, F; DE LUCCHI, O; GUNEY, M; BALCI, M

doi:10.1002/hlca.200390285

Makale Tam Makale Uluslararası 2003

Cyclotrimerization of benzobarrelene: Synthesis of new isomeric barrelene architectures

Arif Daştan, F FABRIS, O DE LUCCHI, M GUNEY, M BALCI

HELVETICA CHIMICA ACTA Cilt 86 · Sayı 10 · ss. 3411–3416 · 01.01.2003

DOI ile aç

Özet

The cyclotrimerization reaction of benzobarrelene derivatives was investigated. Dibromobenzobarrelene 10 was converted to the bromostannyl derivative 11, which was used as the substrate of the cyclotrimerization reaction. Thus. reaction of 11, with copper(I) thiophene-2-carboxylate (CuTC) gave a mixture of the isomeric cyclotrimers 5 and 6 and the dimers 12 and 13, in addition to a trace of protodestannylated bromoalkene 14 (Scheme 2).

Atıf için künye

Daştan, A., FABRIS, F., DE LUCCHI, O., GUNEY, M., & BALCI, M. (2003). Cyclotrimerization of benzobarrelene: Synthesis of new isomeric barrelene architectures. HELVETICA CHIMICA ACTA, 86(10), 3411–3416. https://doi.org/10.1002/hlca.200390285

BibTeX

@article{dastan2003-70693,
  author = {Daştan, Arif and FABRIS, F and DE LUCCHI, O and GUNEY, M and BALCI, M},
  title = {Cyclotrimerization of benzobarrelene: Synthesis of new isomeric barrelene architectures},
  journal = {HELVETICA CHIMICA ACTA},
  year = {2003},
  volume = {86},
  number = {10},
  pages = {3411--3416},
  issn = {0018-019X},
  doi = {10.1002/hlca.200390285},
  url = {https://akademik.atauni.edu.tr/yayinlar/70693-cyclotrimerization-of-benzobarrelene-synthesis-of-new-isomeric-barrelene}
}