Makale
Tam Makale
Uluslararası
2001
A new method for the synthesis of stipitatic acid isomers: Photooxygenation of ethyl 6H-cyclohepta[d][1,3]dioxole-6-carboxylate
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Sayı 18 · ss. 3519–3522 · 01.09.2001
Özet
Photooxygenation of the cycloheptatriene derivative 9 gave the bicyclic endoperoxide 14. Cleavage of the peroxide linkage in 14 with thiourea resulted in the formation of 16. Treatment of the endoperoxide 14 with a catalytic amount of triethylamine provided a new isomer of stipitatic acid 11, and 16. Pyrolysis or the CoTPP (TPP = tetraphenylporphyrin) catalyzed reaction of 14 resulted in the formation of iso-stipitatic acid 10, and 18,
Anahtar kelimeler
Natural products
PEROXIDES
BICYCLIC ENDOPEROXIDES
singlet oxygen
PHOTOCHEMISTRY
fused-ring systems
Atıf için künye
Daştan, A., Saracoglu, N., & BALCI, M. (2001). A new method for the synthesis of stipitatic acid isomers: Photooxygenation of ethyl 6H-cyclohepta[d][1,3]dioxole-6-carboxylate. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(18), 3519–3522.
BibTeX
@article{dastan2001-70682,
author = {Daştan, Arif and Saracoglu, Nurullah and BALCI, METİN},
title = {A new method for the synthesis of stipitatic acid isomers: Photooxygenation of ethyl 6H-cyclohepta[d][1,3]dioxole-6-carboxylate},
journal = {EUROPEAN JOURNAL OF ORGANIC CHEMISTRY},
year = {2001},
number = {18},
pages = {3519--3522},
issn = {1434-193X},
url = {https://akademik.atauni.edu.tr/yayinlar/70682-a-new-method-for-the-synthesis-of-stipitatic-acid-isomers-photooxygenation-of}
}