Synthesis of cyclopentadiene derivatives by retro-Diels-Alder reaction of norbornadiene derivatives

DALKILIC, Erdin; Daştan, Arif

doi:10.1016/j.tet.2015.02.023

Makale Tam Makale Uluslararası 2015

Synthesis of cyclopentadiene derivatives by retro-Diels-Alder reaction of norbornadiene derivatives

Erdin DALKILIC, Arif Daştan

TETRAHEDRON Cilt 71 · Sayı 13 · ss. 1966–1970 · 01.04.2015

DOI ile aç

Özet

Synthesis of cyclopentadiene derivatives starting from norbornadiene was investigated using dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate. The products obtained were either cyclopentadienes or diazines depending on the substituents. The driving force for the formation of these products was discussed in terms of electronic effects. (C) 2015 Elsevier Ltd. All rights reserved.

Anahtar kelimeler

KETONES GENERATION COMPLEXES norbornadiene Alkynes Tetrazine EFFICIENT SYNTHESIS cyclopentadiene retro-Diels-Alder Cyclopentadiene derivatives SUBSTITUTED CYCLOPENTADIENES TETRASUBSTITUTED CYCLOPENTADIENES ZIRCONACYCLOPENTADIENES DIENOPHILES CYCLIZATION

Atıf için künye

DALKILIC, E., & Daştan, A. (2015). Synthesis of cyclopentadiene derivatives by retro-Diels-Alder reaction of norbornadiene derivatives. TETRAHEDRON, 71(13), 1966–1970. https://doi.org/10.1016/j.tet.2015.02.023

BibTeX

@article{dalkilic2015-70677,
  author = {DALKILIC, Erdin and Daştan, Arif},
  title = {Synthesis of cyclopentadiene derivatives by retro-Diels-Alder reaction of norbornadiene derivatives},
  journal = {TETRAHEDRON},
  year = {2015},
  volume = {71},
  number = {13},
  pages = {1966--1970},
  issn = {0040-4020},
  doi = {10.1016/j.tet.2015.02.023},
  url = {https://akademik.atauni.edu.tr/yayinlar/70677-synthesis-of-cyclopentadiene-derivatives-by-retro-diels-alder-reaction-of}
}