Makale
Tam Makale
Uluslararası
2005
Bromination of endo- and exo-benzocyclobutenonorbornene derivatives: neighbour group effect on bromination
JOURNAL OF CHEMICAL RESEARCH-S
Sayı 6 · ss. 348–351 · 01.06.2005
Özet
The electrophilic addition of bromine to 13-anti-bromo-endo-benzocyclobutenonorbornene 7 at-50 +/- 5 degrees C has led in high yield to the formation of the rearranged dibromides 9, 10 and 11. In addition to this, bromination of exo isomer 8 results in formation of rearranged 9 and non rearranged product 10. However, high-temperature bromination of endo 7 and exo isomer 8 at 77 degrees C gave only non-rearranged products. The possible role of a substituent in rearrangements is discussed in these systems.
Atıf için künye
UZUNDUMLU, E., & Daştan, A. (2005). Bromination of endo- and exo-benzocyclobutenonorbornene derivatives: neighbour group effect on bromination. JOURNAL OF CHEMICAL RESEARCH-S(6), 348–351.
BibTeX
@article{uzundumlu2005-70675,
author = {UZUNDUMLU, Eren and Daştan, Arif},
title = {Bromination of endo- and exo-benzocyclobutenonorbornene derivatives: neighbour group effect on bromination},
journal = {JOURNAL OF CHEMICAL RESEARCH-S},
year = {2005},
number = {6},
pages = {348--351},
issn = {0308-2342},
url = {https://akademik.atauni.edu.tr/yayinlar/70675-bromination-of-endo-and-exo-benzocyclobutenonorbornene-derivatives-neighbour}
}