Oxidation reaction of 4-allyl-4-hydroperoxy-2-methoxycyclohexa2,5-dienone in the presence of potassium permanganate without a co-oxidant

Gültekin, Mehmet Serdar; GÖKSU, HAYDAR

Makale Tam Makale Uluslararası 2016

Oxidation reaction of 4-allyl-4-hydroperoxy-2-methoxycyclohexa2,5-dienone in the presence of potassium permanganate without a co-oxidant

Organic Communications Cilt 9 · Sayı 4 · ss. 102–107 · 01.10.2016

Özet

4-Allyl-4-hydroperoxy-2-methoxycyclohexa-2,5-dienone (5) was synthesized by photooxygenation of commercially available Eugenol in the presence of tetraphenylporphyrin (TPP) as a singlet oxygen sensitizer. The brief and one-pot syntheses of some natural product skeletons were conducted using the corresponding allylic hydroperoxide at different temperatures (0 degrees C and room temperature) with potassium permanganate (KMnO4) in mild condition at N-2(g) atm.

Atıf için künye

Gültekin, M. S., & GÖKSU, H. (2016). Oxidation reaction of 4-allyl-4-hydroperoxy-2-methoxycyclohexa2,5-dienone in the presence of potassium permanganate without a co-oxidant. Organic Communications, 9(4), 102–107.

BibTeX

@article{gultekin2016-70489,
  author = {Gültekin, Mehmet Serdar and GÖKSU, HAYDAR},
  title = {Oxidation reaction of 4-allyl-4-hydroperoxy-2-methoxycyclohexa2,5-dienone in the presence of potassium permanganate without a co-oxidant},
  journal = {Organic Communications},
  year = {2016},
  volume = {9},
  number = {4},
  pages = {102--107},
  issn = {1307-6175},
  url = {https://akademik.atauni.edu.tr/yayinlar/70489-oxidation-reaction-of-4-allyl-4-hydroperoxy-2-methoxycyclohexa25-dienone-in-the}
}