One-Pot Synthesis of 1,2,3-Triols from Allylic Hydroperoxides and a Catalytic Amount of OsO4 in Aqueous Acetone

Alp, Cemalettin; Atmaca, Ufuk; Çelik, Murat; Gültekin, Mehmet Serdar

doi:10.1055/s-0029-1217965

Makale Tam Makale Uluslararası 2009 Açık erişimli

One-Pot Synthesis of 1,2,3-Triols from Allylic Hydroperoxides and a Catalytic Amount of OsO4 in Aqueous Acetone

Cemalettin Alp, Ufuk Atmaca, Murat Çelik, Mehmet Serdar Gültekin

Synlett Sayı 17 · ss. 2765–2768 · 21.10.2009

DOI ile aç

Özet

Allylic hydroperoxides were converted into the corresponding triols in the presence of a catalytic amount of OSO4. The present reaction involves regeneration of active osmium species by the hydroperoxide functionality and occurs in a diastereoselective manner to form triols in high yields. A plausible mechanism for the formation of 1,2,3-triols from allylic hydroperoxide is presented.

Atıf için künye

Alp, C., Atmaca, U., Çelik, M., & Gültekin, M. S. (2009). One-Pot Synthesis of 1,2,3-Triols from Allylic Hydroperoxides and a Catalytic Amount of OsO4 in Aqueous Acetone. Synlett(17), 2765–2768. https://doi.org/10.1055/s-0029-1217965

BibTeX

@article{alp2009-70477,
  author = {Alp, Cemalettin and Atmaca, Ufuk and Çelik, Murat and Gültekin, Mehmet Serdar},
  title = {One-Pot Synthesis of 1,2,3-Triols from Allylic Hydroperoxides and a Catalytic Amount of OsO4 in Aqueous Acetone},
  journal = {Synlett},
  year = {2009},
  number = {17},
  pages = {2765--2768},
  issn = {0936-5214},
  doi = {10.1055/s-0029-1217965},
  url = {https://akademik.atauni.edu.tr/yayinlar/70477-one-pot-synthesis-of-123-triols-from-allylic-hydroperoxides-and-a-catalytic}
}