A facile synthesis of vicinal cis-diols from olefins catalyzed by in situ generated MnxOy nanoaggregates
Özet
A novel protocol for the practical and green synthesis of vicinal cis-diols from 10.0 mmol olefins by using 5.0 mmol KMnO4 as oxidant and 30.0 mmol H2O2 as co-oxidant is reported. The presented procedure is easy to carry out and enables the direct transformation of linear and cyclic alkenes to the corresponding vicinal cis-diols. The synthesis of vicinal cis-diols by dihydroxylation of olefins with a KMnO4/H2O2 system was catalyzed by in situ generatedMnxOy nanoaggregates. The use of H2O2 as a co-oxidant is the key for the protocol to synthesize vicinal cis-diols in high yields, because it assists the oxidation of MnxOy nanoaggregates, which have an active role in the oxidation reaction medium.
Atıf için künye
DALMIZRAK, D., GÖKSU, H., & Gültekin, M. S. (2015). A facile synthesis of vicinal cis-diols from olefins catalyzed by in situ generated MnxOy nanoaggregates. RSC advances, 5(27), 20751–20755. https://doi.org/10.1039/c5ra01646k
BibTeX
@article{dalmizrak2015-70475,
author = {DALMIZRAK, Digdem and GÖKSU, Haydar and Gültekin, Mehmet Serdar},
title = {A facile synthesis of vicinal cis-diols from olefins catalyzed by in situ generated MnxOy nanoaggregates},
journal = {RSC advances},
year = {2015},
volume = {5},
number = {27},
pages = {20751--20755},
issn = {2046-2069},
doi = {10.1039/c5ra01646k},
url = {https://akademik.atauni.edu.tr/yayinlar/70475-a-facile-synthesis-of-vicinal-cis-diols-from-olefins-catalyzed-by-in-situ}
}