Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands
Özet
A new Pb(II) complex, [Pb(bp)(2)(btfa)(2)] 1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H-1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions in 1 is eight, with the PbN4O4 coordination polyhedron containing a stereochemically inactive electron lone pair with holodirected coordination spheres. In solid state, there are pi...pi, CH...F, CH...O, and F...F interactions between adjacent units to generate 3D supramolecular structure.
Atıf için künye
Hosseini, S., Marandi, F., Şahin, E., & Musevi, S. J. (2013). Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands. JOURNAL OF CHEMISTRY. https://doi.org/10.1155/2013/159125
BibTeX
@article{hosseini2013-66824,
author = {Hosseini, Saeideh and Marandi, Farzin and Şahin, Ertan and Musevi, Seyid Javad},
title = {Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands},
journal = {JOURNAL OF CHEMISTRY},
year = {2013},
issn = {2090-9063},
doi = {10.1155/2013/159125},
url = {https://akademik.atauni.edu.tr/yayinlar/66824-synthesis-crystal-structure-and-thermal-properties-of-leadii-complex-with}
}