An intramolecular substitution of hydroperoxy-endoperoxide to a bis-endoperoxide

Horasan, Nurhan; Şahin, Ertan; Kara, Yunus

doi:10.1021/ol060272s

Makale Tam Makale Uluslararası 2006

An intramolecular substitution of hydroperoxy-endoperoxide to a bis-endoperoxide

Nurhan Horasan, Ertan Şahin, Yunus Kara

ORGANIC LETTERS Cilt 8 · Sayı 9 · ss. 1791–1793 · 27.04.2006

DOI ile aç

Özet

A new and stereospecitic synthesis for bis-endoperoxide has been developed starting from tetrahydronaphthalene. Photooxygenation of tetrahydronaphthalene resulted in the formation of hydroperoxy-endoperoxide. The bromination reaction of hydroperoxy-endoperoxide gave bis-endoperoxide, whose exact configuration has been determined by X-ray analysis. The lowest-energy conformer of bis-endoperoxide is the boat-chair form.

Atıf için künye

Horasan, N., Şahin, E., & Kara, Y. (2006). An intramolecular substitution of hydroperoxy-endoperoxide to a bis-endoperoxide. ORGANIC LETTERS, 8(9), 1791–1793. https://doi.org/10.1021/ol060272s

BibTeX

@article{horasan2006-66806,
  author = {Horasan, Nurhan and Şahin, Ertan and Kara, Yunus},
  title = {An intramolecular substitution of hydroperoxy-endoperoxide to a bis-endoperoxide},
  journal = {ORGANIC LETTERS},
  year = {2006},
  volume = {8},
  number = {9},
  pages = {1791--1793},
  issn = {1523-7060},
  doi = {10.1021/ol060272s},
  url = {https://akademik.atauni.edu.tr/yayinlar/66806-an-intramolecular-substitution-of-hydroperoxy-endoperoxide-to-a-bis-endoperoxide}
}