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Makale Tam Makale Uluslararası 2016

Cycloaddition reaction of spiro[2.4]hepta-4,6-dien-1-ylmethanol and PTAD: a new rearrangement

Halil SENOL, Cetin BAYRAK, Abdullah MENZEK, Ertan Şahin, Murat KARAKUS

TETRAHEDRON Cilt 72 · Sayı 20 · ss. 2587–2592 · 19.05.2016
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Özet

Reaction of spiro[2.4]hepta-4,6-dien-1-ylmethanol (3) with phenyltriazolinedione (PTAD) gave 4-phenyl-1-[(3aR(S),6S(R))-1a, 2,3a, 6-tetrahydro-1H-cyclopenta[b]cyclopropa[c]furan-6-yl]-1,2,4-triazolidine-3,5-dione (7) via a novel rearrangement. The structure of this rearranged product was determined by spectroscopic methods and by experimentation. Influences of functional groups on the rearrangement and formation of 7 were discussed. (C) 2016 Elsevier Ltd. All rights reserved.

Atıf için künye

SENOL, H., BAYRAK, C., MENZEK, A., Şahin, E., & KARAKUS, M. (2016). Cycloaddition reaction of spiro[2.4]hepta-4,6-dien-1-ylmethanol and PTAD: a new rearrangement. TETRAHEDRON, 72(20), 2587–2592. https://doi.org/10.1016/j.tet.2016.03.094

BibTeX
@article{senol2016-66803,
  author = {SENOL, Halil and BAYRAK, Cetin and MENZEK, Abdullah and Şahin, Ertan and KARAKUS, Murat},
  title = {Cycloaddition reaction of spiro[2.4]hepta-4,6-dien-1-ylmethanol and PTAD: a new rearrangement},
  journal = {TETRAHEDRON},
  year = {2016},
  volume = {72},
  number = {20},
  pages = {2587--2592},
  issn = {0040-4020},
  doi = {10.1016/j.tet.2016.03.094},
  url = {https://akademik.atauni.edu.tr/yayinlar/66803-cycloaddition-reaction-of-spiro24hepta-46-dien-1-ylmethanol-and-ptad-a-new}
}