Copper(II) 2-Benzoylbenzoate Complexes Containing 2-Pyridilmethanol and 2-Pyridilethanol: Synthesis, Crystal Structures, Spectroscopic, and Thermal Properties
Özet
Two new copper(II) complexes, [Cu(bba)(2)(pymet)(2)] 1 and [Cu(bba)(2)(pyet)(2)] 2, have been synthesized and characterized by elemental analysis, thermal analysis, UV-Vis, and IR spectroscopic techniques. Single-crystal X-ray analysis of 1 and 2 revealed that the geometries are octahedral. 1 crystallizes in the monoclinic crystal system with space group P2(1)/n, while 2 crystallizes in the triclinic crystal system with the space group P-1. 2-benzoylbenzoic acid ligand behaves as a monodentate, while 2-pyridilmethanol and 2-pyridilethanol ligands act as a bidentate in two complexes. Thermal analysis show that two decomposition stages of the investigated complex 1 and 2, stable up to similar to 160 degrees C.
Atıf için künye
ÇAĞLAR, S., Saykal, T., BÜYÜKGÜNGÖR, O., & Şahin, E. (2014). Copper(II) 2-Benzoylbenzoate Complexes Containing 2-Pyridilmethanol and 2-Pyridilethanol: Synthesis, Crystal Structures, Spectroscopic, and Thermal Properties. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 44(9), 1234–1242. https://doi.org/10.1080/15533174.2013.799491
BibTeX
@article{caglar2014-66783,
author = {ÇAĞLAR, SEMA and Saykal, Tuba and BÜYÜKGÜNGÖR, ORHAN and Şahin, Ertan},
title = {Copper(II) 2-Benzoylbenzoate Complexes Containing 2-Pyridilmethanol and 2-Pyridilethanol: Synthesis, Crystal Structures, Spectroscopic, and Thermal Properties},
journal = {SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY},
year = {2014},
volume = {44},
number = {9},
pages = {1234--1242},
issn = {1553-3174},
doi = {10.1080/15533174.2013.799491},
url = {https://akademik.atauni.edu.tr/yayinlar/66783-copperii-2-benzoylbenzoate-complexes-containing-2-pyridilmethanol-and-2}
}