Addition of hypobromous acid to 1-phenylcycloalkenes

Ceylan, M.; Findik, E.; Şahin, Ertan; Kazaz, Cavit

doi:10.1007/s11172-009-0321-y

Makale Tam Makale Uluslararası 2009

Addition of hypobromous acid to 1-phenylcycloalkenes

M. Ceylan, E. Findik, Ertan Şahin, Cavit Kazaz

RUSSIAN CHEMICAL BULLETIN Cilt 58 · Sayı 11 · ss. 2299–2303 · 01.11.2009

DOI ile aç

Özet

Reaction of 1-phenylcyclooctene and 1-phenylcycloheptene with N-bromosuccinimide (NBS) in aqueous DMSO gives the corresponding 3-bromo-2-phenylcycloalkenes and 2-phenylcycloalk-2-enols in a ratio of 3 : 1. Unlike them, 1-phenylcyclohexene gives a mixture of 3-bromo-2-phenylcyclohexene and 2-bromo-1-phenylcyclohexanol. The oxidation of allylic alcohols with pyridinium chlorochromate afforded the corresponding alpha,beta-unsaturated ketones.

Anahtar kelimeler

ALPHA 1-phenylcycloalkenes allylic bromides allylic alcohols N-bromosuccinimide beta-enones BENZENE

Atıf için künye

Ceylan, M., Findik, E., Şahin, E., & Kazaz, C. (2009). Addition of hypobromous acid to 1-phenylcycloalkenes. RUSSIAN CHEMICAL BULLETIN, 58(11), 2299–2303. https://doi.org/10.1007/s11172-009-0321-y

BibTeX

@article{ceylan2009-66747,
  author = {Ceylan, M. and Findik, E. and Şahin, Ertan and Kazaz, Cavit},
  title = {Addition of hypobromous acid to 1-phenylcycloalkenes},
  journal = {RUSSIAN CHEMICAL BULLETIN},
  year = {2009},
  volume = {58},
  number = {11},
  pages = {2299--2303},
  issn = {1066-5285},
  doi = {10.1007/s11172-009-0321-y},
  url = {https://akademik.atauni.edu.tr/yayinlar/66747-addition-of-hypobromous-acid-to-1-phenylcycloalkenes}
}