A New, Fast and Easy Strategy for One-pot Synthesis of Full Substituted Cyclopropanes: Direct Transformation of Aldehydes to 3-Aryl-1,1,2,2-tetracyanocyclopropanes
Özet
A new, fast and easy method for one-pot reaction of aromatic aldehydes and dialdehydes with malononitrile and cyanogen bromide has been developed to afford full substituted 3-arylcyclopropane-1,1,2,2-tetracarbonitriles in excellent yields in very short time (about 5 seconds). The structures elucidations were characterized by IR, H-1 NMR, C-13 NMR, mass spectrometry and X-ray crystallography techniques. For these compounds the crystallographic data showed two structures in mirror image in solid case and one distinct structure in solution. The reaction mechanism was discussed.
Atıf için künye
Pesyan, N. N., Kimia, M. A., Jalilzadeh, M., & Şahin, E. (2013). A New, Fast and Easy Strategy for One-pot Synthesis of Full Substituted Cyclopropanes: Direct Transformation of Aldehydes to 3-Aryl-1,1,2,2-tetracyanocyclopropanes. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 60(1), 35–44. https://doi.org/10.1002/jccs.201200189
BibTeX
@article{pesyan2013-66737,
author = {Pesyan, Nader Noroozi and Kimia, Mohammad Ali and Jalilzadeh, Mohammad and Şahin, Ertan},
title = {A New, Fast and Easy Strategy for One-pot Synthesis of Full Substituted Cyclopropanes: Direct Transformation of Aldehydes to 3-Aryl-1,1,2,2-tetracyanocyclopropanes},
journal = {JOURNAL OF THE CHINESE CHEMICAL SOCIETY},
year = {2013},
volume = {60},
number = {1},
pages = {35--44},
issn = {0009-4536},
doi = {10.1002/jccs.201200189},
url = {https://akademik.atauni.edu.tr/yayinlar/66737-a-new-fast-and-easy-strategy-for-one-pot-synthesis-of-full-substituted}
}