Synthesis, Crystal Structure and Characterisation of a Novel Mononuclear Boron-Schiff Base Complex
Özet
A novel boron complex C(21)H(19)NO(3)B was obtained from phenylboronic acid and N-(2-hydroxybenzyl) salicylaldimine in methanol media. The structure was characterized by using IR, (1)H-NMR spectroscopy, thermogravimetric analysis (TGA) and X-ray crystallography. In this complex, boron atom is coordinated with the two phenolic oxygen atoms and iminic nitrogen and a carbon atom of a phenyl group in a tetrahedral structure as expected. Although the bond distances around the boron atom were different from one another, the bond angles of O1-B1-O2, O1-B1-N1, 02-B1-N1, O1-B1-C1 and N1-B1-C1 were found close to ideal values as 110.4(5), 108.3(5), 108.4(4), 109.3(5) and 108(2)degrees, respectively. By thermogravimetric analysis it was concluded that the methyl alcohol left the complex at 160 degrees C and a new coordination sphere was formed.
Atıf için künye
Bilgic, R., Şahin, E., Kenar, A., Atakol, O., & Kazaz, C. (2009). Synthesis, Crystal Structure and Characterisation of a Novel Mononuclear Boron-Schiff Base Complex. MAIN GROUP METAL CHEMISTRY, 32(2), 85–92.
BibTeX
@article{bilgic2009-66701,
author = {Bilgic, Rauf and Şahin, Ertan and Kenar, Adnan and Atakol, Orhan and Kazaz, Cavit},
title = {Synthesis, Crystal Structure and Characterisation of a Novel Mononuclear Boron-Schiff Base Complex},
journal = {MAIN GROUP METAL CHEMISTRY},
year = {2009},
volume = {32},
number = {2},
pages = {85--92},
issn = {0334-7575},
url = {https://akademik.atauni.edu.tr/yayinlar/66701-synthesis-crystal-structure-and-characterisation-of-a-novel-mononuclear-boron}
}