Synthesis, Crystal Structure, and Spectroscopic Studies of N-(4-Bromobenzylidene)-N '-(2-Pyridyl) Hydrazine Schiff Base Molecule
Özet
A new Schiff base complex N-(4-bromobenzylidene)-N'-(2-pyridyl) hydrazine, C12H10N3Br, has been synthesized and characterized by elemental analyses, mass, H-1 NMR, ultraviolet-visible (UV-VIS), and IR spectroscopy and single-crystal X-ray determination. The p-Br-benzene and pyridine rings are almost planar and the dihedral angle between the planes is 11.1(3)degrees. The crystal structure is stabilized by intermolecular N-H center dot center dot center dot N-Py hydrogen bonding interaction. X-ray diffraction analyses show that N-(4-bromobenzylidene)-N'-(2-pyridyl) hydrazine Schiff base molecule crystallizes in the monoclinic system, P2(1)/c space group, a = 5.611(5) angstrom, b = 19.566(5) angstrom, c = 10.715(5) angstrom, beta = 98.766(5)degrees, and V = 1162.60(12) angstrom(3).
Atıf için künye
TUNÇ, T., Tezcan, H., Şahin, E., & Dilek, N. (2012). Synthesis, Crystal Structure, and Spectroscopic Studies of N-(4-Bromobenzylidene)-N '-(2-Pyridyl) Hydrazine Schiff Base Molecule. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 552, 194–208. https://doi.org/10.1080/15421406.2011.591702
BibTeX
@article{tunc2012-66692,
author = {TUNÇ, TUNCAY and Tezcan, Habibe and Şahin, Ertan and Dilek, Nefise},
title = {Synthesis, Crystal Structure, and Spectroscopic Studies of N-(4-Bromobenzylidene)-N '-(2-Pyridyl) Hydrazine Schiff Base Molecule},
journal = {MOLECULAR CRYSTALS AND LIQUID CRYSTALS},
year = {2012},
volume = {552},
pages = {194--208},
issn = {1542-1406},
doi = {10.1080/15421406.2011.591702},
url = {https://akademik.atauni.edu.tr/yayinlar/66692-synthesis-crystal-structure-and-spectroscopic-studies-of-n-4-bromobenzylidene-n}
}