An Efficient Promising Direction for the Synthesis of Dispirotripiperazine (6-6-6 DSTP) Core
Özet
A new and facile route for the one-pot synthesis of 3,12-dicyano-3,6,9,12-tetraazadispiro[5.2.5(9).2(6)]hexadecane-6,9-diium dibromide as a dispirotripiperazine source was introduced by the simple reaction of 1,4-diazabicyclo[2.2.2]octane (DABCO) with cyanogen bromide (BrCN) under mild condition at room temperature. The hydrolysis of dicyanamide moieties in the prepared dispiro compound gave 3,12-diaza-6,9-diazoniadispiro[5.2.5.2]hexadecane dibromide with the dispirotripiperazine (6-6-6) core. The molecular structure of the new compound was characterized by FT-IR, H-1, C-13, HSQC NMR spectroscopy, mass and CHN analysis, and X-ray crystallography technique.
Sürdürülebilir Kalkınma Amaçları
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SKA 3: Sağlıklı Bireyler
Atıf için künye
Golmohammadi, M., Pesyan, N. N., & Şahin, E. (2024). An Efficient Promising Direction for the Synthesis of Dispirotripiperazine (6-6-6 DSTP) Core. Synthesis (Germany), 56(17), 2742–2746. https://doi.org/10.1055/s-0043-1774930
BibTeX
@article{golmohammadi2024-66690,
author = {Golmohammadi, Mahsa and Pesyan, Nader Noroozi and Şahin, Ertan},
title = {An Efficient Promising Direction for the Synthesis of Dispirotripiperazine (6-6-6 DSTP) Core},
journal = {Synthesis (Germany)},
year = {2024},
volume = {56},
number = {17},
pages = {2742--2746},
issn = {0039-7881},
doi = {10.1055/s-0043-1774930},
url = {https://akademik.atauni.edu.tr/yayinlar/66690-an-efficient-promising-direction-for-the-synthesis-of-dispirotripiperazine-6-6-6}
}