The synthesis of blue emitting 3-Amino-l-hetarylfluorenes and their unprecedented alkylated derivatives

Yalcin, Ergin; Duyar, Halil; Cakmaz, Deniz; Şahin, Ertan; SEFEROĞLU, ZEYNEL

doi:10.1016/j.tet.2019.130464

Makale Tam Makale Uluslararası 2019

The synthesis of blue emitting 3-Amino-l-hetarylfluorenes and their unprecedented alkylated derivatives

Ergin Yalcin, Halil Duyar, Deniz Cakmaz, Ertan Şahin, ZEYNEL SEFEROĞLU

TETRAHEDRON Cilt 75 · Sayı 35 · 30.08.2019

DOI ile aç

Özet

Novel 3-Amino-1-hetarylfluorene derivatives have medicinal uses and challenging transformation in organic synthesis have been synthesized via decyanation process. Surprisingly, the alkylated compounds derived from 3-Amino-1-hetarylfluorenes were obtained via further nucleophilic substitution to the 9-C and 3-N positions of the fluorene ring because of the harsh reaction condition employed. The synthesized compounds were characterized by spectroscopic techniques as well as X-ray single crystal diffraction analysis. This new family of blue emitting fluorene derivatives have low to moderate quantum yields (the largest value of Phi(F) = 0.52 for compound 15). (C) 2019 Elsevier Ltd. All rights reserved.

Anahtar kelimeler

REDUCTION nanoparticles Fluorescent dyes ALCOHOLS catalysts EFFICIENT SYNTHESIS 3-Amino-1-hetaryl-2 4-dicyanofluorenes 3-Amino-1-hetarylfluorene derivatives Decyanation reaction Blue emitting fluorenes SELECTIVE HYDROGENATION FLUORENE ARYLIDENEMALONODINITRILES NITRO

Atıf için künye

Yalcin, E., Duyar, H., Cakmaz, D., Şahin, E., & SEFEROĞLU, Z. (2019). The synthesis of blue emitting 3-Amino-l-hetarylfluorenes and their unprecedented alkylated derivatives. TETRAHEDRON, 75(35). https://doi.org/10.1016/j.tet.2019.130464

BibTeX

@article{yalcin2019-66669,
  author = {Yalcin, Ergin and Duyar, Halil and Cakmaz, Deniz and Şahin, Ertan and SEFEROĞLU, ZEYNEL},
  title = {The synthesis of blue emitting 3-Amino-l-hetarylfluorenes and their unprecedented alkylated derivatives},
  journal = {TETRAHEDRON},
  year = {2019},
  volume = {75},
  number = {35},
  issn = {0040-4020},
  doi = {10.1016/j.tet.2019.130464},
  url = {https://akademik.atauni.edu.tr/yayinlar/66669-the-synthesis-of-blue-emitting-3-amino-l-hetarylfluorenes-and-their}
}