Conformational control on remote stereochemistry in the intramolecular Pauson-Khand reactions of enynes tethered to homoallyl and homopropargyl alcohols
Özet
An intramolecular Pauson-Khand reaction of enynes derived from homoallyl and homopropargyl alcohols is described. 2-Furyl substituted homoallyl and homopropargyl alcohols are easily and efficiently resolved through enzymatic resolution in a high ee (93-99%) with a known stereochemistry. Each enantiomerically enriched enyne affords the conformationally most stable diastereomeric cyclopenta[c]pyran ring system. (c) 2006 Elsevier Ltd. All rights reserved.
Atıf için künye
Sezer, S., Ozdemirhan, D., Şahin, E., & Tanyeli, C. (2006). Conformational control on remote stereochemistry in the intramolecular Pauson-Khand reactions of enynes tethered to homoallyl and homopropargyl alcohols. TETRAHEDRON-ASYMMETRY, 17(21), 2981–2986. https://doi.org/10.1016/j.tetasy.2006.11.012
BibTeX
@article{sezer2006-66664,
author = {Sezer, Serdar and Ozdemirhan, Devrim and Şahin, Ertan and Tanyeli, Cihangir},
title = {Conformational control on remote stereochemistry in the intramolecular Pauson-Khand reactions of enynes tethered to homoallyl and homopropargyl alcohols},
journal = {TETRAHEDRON-ASYMMETRY},
year = {2006},
volume = {17},
number = {21},
pages = {2981--2986},
issn = {0957-4166},
doi = {10.1016/j.tetasy.2006.11.012},
url = {https://akademik.atauni.edu.tr/yayinlar/66664-conformational-control-on-remote-stereochemistry-in-the-intramolecular-pauson}
}