One-Dimensional Ni(II) and Cu(II) Coordination Polymers Containing Syn-Syn Thiophene-2,5-dicarboxylate and Propane-1,3-diamine
Özet
New thiophene-2,5-dicarboxylate complexes with the formula of [M(mu-tdc)(pen)(2)] (n) (M = Ni(II) (1) and Cu(II) (2), pen = propane-1,3-diamine, tdc = thiophene-2,5-dicarboxylate) have been synthesized and characterized by using thermal (TG/DTG, DTA and MS) analysis, IR and UV-Vis. spectroscopies, magnetic measurement and single crystal X-Ray diffraction techniques. The Ni(II) and Cu(II) ions are distorted octahedrally coordinated by two oxygen atoms of two bridging thiophene-2,5-dicarboxylate ligands and four nitrogen atoms of the trans-pen ligands. The polymeric chains are connected together by hydrogen bonds interactions, forming three-dimensional network.
Anahtar kelimeler
Atıf için künye
YEŞİLEL, O. Z., Ilker, I., & Şahin, E. (2011). One-Dimensional Ni(II) and Cu(II) Coordination Polymers Containing Syn-Syn Thiophene-2,5-dicarboxylate and Propane-1,3-diamine. Journal of Inorganic and Organometallic Polymers and Materials, 21(1), 103–109. https://doi.org/10.1007/s10904-010-9414-1
BibTeX
@article{yesilel2011-66647,
author = {YEŞİLEL, OKAN ZAFER and Ilker, Inci and Şahin, Ertan},
title = {One-Dimensional Ni(II) and Cu(II) Coordination Polymers Containing Syn-Syn Thiophene-2,5-dicarboxylate and Propane-1,3-diamine},
journal = {Journal of Inorganic and Organometallic Polymers and Materials},
year = {2011},
volume = {21},
number = {1},
pages = {103--109},
issn = {1574-1443},
doi = {10.1007/s10904-010-9414-1},
url = {https://akademik.atauni.edu.tr/yayinlar/66647-one-dimensional-niii-and-cuii-coordination-polymers-containing-syn-syn-thiophene}
}