Two independent and consecutive Michael addition of 1,3-dimethylbarbituric acid to (2,6-diarylidene)cyclohexanone: Flying-bird-shaped 2D-polymeric structure
Özet
Two independent and consecutive intermolecular Michael addition of 1,3-dimethylbarbituric acid to 2,6-diarylidenecyclohexanone as an alpha,beta-unsaturated ketone leads to synthesis of a new type of meso form 5,5 '-((2-oxocyclohexane-1,3-diyl)bis(arylmethylene))bis(1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione) in good yield. These compounds showed a 2D-polymeric structure via intermolecular H-bonds. Structure elucidation is carried out by H-1 NMR, C-13 NMR, FT-IR, and X-ray diffraction analyses. A plausible reaction mechanism is discussed.
Anahtar kelimeler
Atıf için künye
Pesyan, N. N., Mousavi, S., & Şahin, E. (2022). Two independent and consecutive Michael addition of 1,3-dimethylbarbituric acid to (2,6-diarylidene)cyclohexanone: Flying-bird-shaped 2D-polymeric structure. HETEROCYCLIC COMMUNICATIONS, 28(1), 44–50. https://doi.org/10.1515/hc-2022-0009
BibTeX
@article{pesyan2022-66645,
author = {Pesyan, Nader Noroozi and Mousavi, Saman and Şahin, Ertan},
title = {Two independent and consecutive Michael addition of 1,3-dimethylbarbituric acid to (2,6-diarylidene)cyclohexanone: Flying-bird-shaped 2D-polymeric structure},
journal = {HETEROCYCLIC COMMUNICATIONS},
year = {2022},
volume = {28},
number = {1},
pages = {44--50},
issn = {0793-0283},
doi = {10.1515/hc-2022-0009},
url = {https://akademik.atauni.edu.tr/yayinlar/66645-two-independent-and-consecutive-michael-addition-of-13-dimethylbarbituric-acid}
}