An unsymmetrical ferrocene based azine and its Cu(II) complex: Spectroscopy, crystal structure, electrochemistry and DFT calculations

Karaoglu, Kaan; Serbest, Kerim; Emirik, Mustafa; Şahin, Ertan

doi:10.1016/j.jorganchem.2014.10.021

Makale Tam Makale Uluslararası 2015

An unsymmetrical ferrocene based azine and its Cu(II) complex: Spectroscopy, crystal structure, electrochemistry and DFT calculations

Kaan Karaoglu, Kerim Serbest, Mustafa Emirik, Ertan Şahin

JOURNAL OF ORGANOMETALLIC CHEMISTRY Cilt 775 · ss. 80–87 · 01.01.2015

DOI ile aç

Özet

An unsymmetrical ferrocenyl-substituted azine ligand and its Cu(II) complex have been prepared in this study. The redox active ferrocene-based azine ligand was obtained by condensation of 2-methanehydrazonoylphenol and ferrocenecarboxaldehyde. Structures of the ligand and its Cu(II) complex have been characterized by IR, UV-vis, NMR, X-ray, magnetic measurements and TG techniques. Redox behaviors of the ligand and its Cu(II) complex have been investigated by cyclic voltammetry. Structural parameters and spectroscopic properties of the azine ligand containing ferrocenyl unit and its Cu(II) complex were calculated by DFT and TD-DFT/CPCM methods and compared with the experimental results. (C) 2014 Elsevier B.V. All rights reserved.

Anahtar kelimeler

CHEMISTRY CRYSTAL-STRUCTURE REACTIVITY SCHIFF-BASES METAL-COMPLEXES NI(II) DFT calculations COPPER(II) COMPLEXES DNA cleavage Azine Ferrocene Electronic transitions LIGAND REDOX ENVIRONMENT

Atıf için künye

Karaoglu, K., Serbest, K., Emirik, M., & Şahin, E. (2015). An unsymmetrical ferrocene based azine and its Cu(II) complex: Spectroscopy, crystal structure, electrochemistry and DFT calculations. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 775, 80–87. https://doi.org/10.1016/j.jorganchem.2014.10.021

BibTeX

@article{karaoglu2015-66636,
  author = {Karaoglu, Kaan and Serbest, Kerim and Emirik, Mustafa and Şahin, Ertan},
  title = {An unsymmetrical ferrocene based azine and its Cu(II) complex: Spectroscopy, crystal structure, electrochemistry and DFT calculations},
  journal = {JOURNAL OF ORGANOMETALLIC CHEMISTRY},
  year = {2015},
  volume = {775},
  pages = {80--87},
  issn = {0022-328X},
  doi = {10.1016/j.jorganchem.2014.10.021},
  url = {https://akademik.atauni.edu.tr/yayinlar/66636-an-unsymmetrical-ferrocene-based-azine-and-its-cuii-complex-spectroscopy-crystal}
}