Boric acid complexes with organic biomolecules: Mono-chelate complexes with salicylic and glucuronic acids
Özet
Two mono-chelate borate complexes, lithium mono-salicylatoborate and sodium mono-glucuronatoborate, are reported for the first time. The complexes were isolated from aqueous solutions and characterized by FTIR (Fourier Transform Infrared) and C-13 MAS (Magic Angle Spinning) NMR techniques. Thermal stabilities of the complexes were examined by recording their TGA (Thermogravimetric Analysis) curves. Lithium mono-salicylatoborate, Li[B(Sal)(OH)(2)], was isolated in crystal form and presented as a novel hybrid metal-organic framework possessing zeolitic structure. X-ray analysis revealed an original crystal structure constructed with solvate-free lithium ions adopting two different types of coordination polyhedra, corner-sharing LiO4 (tetrahedral) and LiO5 (distorted square pyramidal), in the same framework. (C) 2010 Elsevier B.V. All rights reserved.
Anahtar kelimeler
Atıf için künye
KÖSE, D. A., Zumreoglu-Karan, B., HÖKELEK, T., & Şahin, E. (2010). Boric acid complexes with organic biomolecules: Mono-chelate complexes with salicylic and glucuronic acids. Inorganica Chimica Acta, 363(14), 4031–4037. https://doi.org/10.1016/j.ica.2010.08.001
BibTeX
@article{kose2010-66570,
author = {KÖSE, DURSUN ALİ and Zumreoglu-Karan, Birgul and HÖKELEK, TUNCER and Şahin, Ertan},
title = {Boric acid complexes with organic biomolecules: Mono-chelate complexes with salicylic and glucuronic acids},
journal = {Inorganica Chimica Acta},
year = {2010},
volume = {363},
number = {14},
pages = {4031--4037},
issn = {0020-1693},
doi = {10.1016/j.ica.2010.08.001},
url = {https://akademik.atauni.edu.tr/yayinlar/66570-boric-acid-complexes-with-organic-biomolecules-mono-chelate-complexes-with}
}