A New Sodium Borate: Na[B6O8(OH)(3)]center dot 6H(2)O center dot H3BO3
Özet
The structure of [B6H9NaO14, H3BO3, 6H(2)O] was determined by single-crystal X-ray diffraction and further analyzed by FTIR spectroscopy and differential thermal/thermogravimetric analysis. The asymmetric unit contains Na-O polyhedra (distorted octahedron), [B6O8(OH)(3)](-) fundamental building blocks, one free water molecule and one free H3BO3 molecule. In the hexaborate anion, three B3O3 rings are linked by a common oxygen atom with five trigonal and one tetrahedral boron atoms. The hexaborate group is also linked to the oxygenated environment of the sodium atom by three other six-membered rings, each of which involve two boron atoms, three oxygen atoms, and sodium as the joint atom.
Atıf için künye
Kose, D. A., Zumreoglu-Karan, B., HÖKELEK, T., & Şahin, E. (2009). A New Sodium Borate: Na[B6O8(OH)(3)]center dot 6H(2)O center dot H3BO3. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 635(3), 563–566.
BibTeX
@article{kose2009-66559,
author = {Kose, Dursun Ali and Zumreoglu-Karan, Birguel and HÖKELEK, TUNCER and Şahin, Ertan},
title = {A New Sodium Borate: Na[B6O8(OH)(3)]center dot 6H(2)O center dot H3BO3},
journal = {ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE},
year = {2009},
volume = {635},
number = {3},
pages = {563--566},
issn = {0044-2313},
url = {https://akademik.atauni.edu.tr/yayinlar/66559-a-new-sodium-borate-nab6o8oh3center-dot-6h2o-center-dot-h3bo3}
}