Immobilization of a molybdenum-glycine Schiff base complex within the nanocages of zeolite Y with flexible ligand method

EGHBALİ, Paria; Şahin, Ertan; Masteri-Farahani, Majid

doi:10.1007/s10934-016-0234-8

Makale Tam Makale Uluslararası 2017

Immobilization of a molybdenum-glycine Schiff base complex within the nanocages of zeolite Y with flexible ligand method

Paria EGHBALİ, Ertan Şahin, Majid Masteri-Farahani

JOURNAL OF POROUS MATERIALS Cilt 24 · Sayı 1 · ss. 39–44 · 01.02.2017

DOI ile aç

Özet

Immobilization of a molybdenum-glycine Schiff base complex onto the supercages of zeolite Y was achieved through the flexible ligand method. The prepared material was characterized by different physicochemical techniques. FT-IR spectroscopy confirmed the immobilization of the complex onto the nanocages of zeolite Y. X-ray diffraction analysis revealed that textural properties of zeolite Y support were preserved during the immobilization process. Nitrogen adsorption-desorption analysis demonstrated the decrease in surface area of the prepared material in comparison with parent zeolite Y. Inductively coupled plasma optical emission spectroscopy showed the presence of 0.75 mmol g(-1) molybdenum in the final material. The obtained material exhibited high catalytic activity, stability, and recyclability in the epoxidation of olefins with tert-butylhydroperoxide as oxidant.

Anahtar kelimeler

amino acids EPOXIDATION Schiff base CU(II) COMPLEXES Molybdenum Glycine Zeolite Y MESOPOROUS MCM-41 MATERIALS LIQUID-PHASE HYDROXYLATION NANOCOMPOSITE MATERIALS ZEOLITE-Y)/GUEST MN(II) CATALYTIC-OXIDATION HOST (NANOPORES MOLECULAR-OXYGEN

Atıf için künye

EGHBALİ, P., Şahin, E., & Masteri-Farahani, M. (2017). Immobilization of a molybdenum-glycine Schiff base complex within the nanocages of zeolite Y with flexible ligand method. JOURNAL OF POROUS MATERIALS, 24(1), 39–44. https://doi.org/10.1007/s10934-016-0234-8

BibTeX

@article{eghbali2017-66520,
  author = {EGHBALİ, Paria and Şahin, Ertan and Masteri-Farahani, Majid},
  title = {Immobilization of a molybdenum-glycine Schiff base complex within the nanocages of zeolite Y with flexible ligand method},
  journal = {JOURNAL OF POROUS MATERIALS},
  year = {2017},
  volume = {24},
  number = {1},
  pages = {39--44},
  issn = {1380-2224},
  doi = {10.1007/s10934-016-0234-8},
  url = {https://akademik.atauni.edu.tr/yayinlar/66520-immobilization-of-a-molybdenum-glycine-schiff-base-complex-within-the-nanocages}
}