Gamma-irradiated calcium succinate monohydrate single crystal investigation with EPR technique
Özet
In this study, EPR investigation of gamma-irradiated calcium succinate monohydrate [CaC(4)H(4)O(4)center dot H(2)O] single crystal has been carried out at room temperature. The compound crystallizes in monoclinic symmetry with the unit-cell dimensions: a = 11.952(2) angstrom. b = 9.691(2)angstrom, c = 11.606(2)angstrom, beta = 108.81(1)degrees. The observed lines in the EPR spectra reveal the formation of (C)over dotH(alpha)CH(beta 1)H(beta 2) radical after irradiating [CaC(4)H(4)O(4)center dot H(2)O] single crystal. The angular variations of EPR spectra have shown that the radical type has only one site in three perpendicular planes. The principal g and a values and direction cosines of (C)over dotH(alpha)CH(beta 1)H(beta 2) radical have been determined. (C) 2011 Elsevier B.V. All rights reserved.
Atıf için künye
Yarbasi, Z., KARABULUT, B., & Karabulut, A. (2011). Gamma-irradiated calcium succinate monohydrate single crystal investigation with EPR technique. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 83(1), 337–339. https://doi.org/10.1016/j.saa.2011.08.040
BibTeX
@article{yarbasi2011-62464,
author = {Yarbasi, Zeynep and KARABULUT, BÜNYAMİN and Karabulut, Abdulhalik},
title = {Gamma-irradiated calcium succinate monohydrate single crystal investigation with EPR technique},
journal = {Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy},
year = {2011},
volume = {83},
number = {1},
pages = {337--339},
issn = {1386-1425},
doi = {10.1016/j.saa.2011.08.040},
url = {https://akademik.atauni.edu.tr/yayinlar/62464-gamma-irradiated-calcium-succinate-monohydrate-single-crystal-investigation-with}
}