Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins

Dağalan, Ziya; Kocak, Ramazan; Daştan, Arif; Nişancı, Bilal

doi:10.1021/acs.orglett.2c02627

Makale Tam Makale Uluslararası 2022

Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins

Ziya Dağalan, Ramazan Kocak, Arif Daştan, Bilal Nişancı

ORGANIC LETTERS Cilt 24 · ss. 8261–8264 · 18.11.2022

DOI ile aç

Özet

Herein, we report the first metal-free and molecular halogen reagent-free dihomohalogenation methodology by using Selectfluor as an oxidant and tetrabutylammonium bromide/ chloride salts as a halogen source. This effective strategy provides various fluorine-free halogenated products easily in quantitative yields from alkenes, alkynes, and natural products.

Atıf için künye

Dağalan, Z., Kocak, R., Daştan, A., & Nişancı, B. (2022). Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins. ORGANIC LETTERS, 24, 8261–8264. https://doi.org/10.1021/acs.orglett.2c02627

BibTeX

@article{dagalan2022-54191,
  author = {Dağalan, Ziya and Kocak, Ramazan and Daştan, Arif and Nişancı, Bilal},
  title = {Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins},
  journal = {ORGANIC LETTERS},
  year = {2022},
  volume = {24},
  pages = {8261--8264},
  issn = {1523-7060},
  doi = {10.1021/acs.orglett.2c02627},
  url = {https://akademik.atauni.edu.tr/yayinlar/54191-selectfluor-and-tbax-cl-br-mediated-oxidative-chlorination-and-bromination-of}
}