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Makale Tam Makale Uluslararası 2015

A combination of solid-phase extraction and dispersive solid-phase extraction effectively reduces the matrix interference in liquid chromatography-ultraviolet detection during pyraclostrobin analysis in perilla leaves

Waziha Farha, Md. Musfiqur Rahman, Abdelaty Mostafa Abdelaty Hassıbelnaby, Da-I. Jung, Md. Humayun Kabir, Jeong-Heui Choi, Sung-Woo Kim, So Jeong Im, Young-Jun Lee, Ho-Chul Shin, Chan-Hyeok Kwon, Young-Wook Son, Kang-Bong Lee, Jae-Han Shim

Biomedical Chromatography Cilt 29 · Sayı 12 · ss. 1932–1936 · 01.12.2015
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Özet

Perilla leaves contain many interfering substances; thus, it is difficult to protect the analytes during identification and integration. Furthermore, increasing the amount of sample to lower the detection limit worsens the situation. To overcome this problem, we established a new method using a combination of solid-phase extraction and dispersive solid-phase extraction to analyze pyraclostrobin in perilla leaves by liquid chromatography with ultraviolet absorbance detection. The target compound was quantitated by external calibration with a good determination coefficient (R-2 = 0.997). The method was validated (in triplicate) with three fortification levels, and 79.06- 89.10% of the target compound was recovered with a relative standard deviation <4. The limits of detection and quantification were 0.0033 and 0.01 mg/kg, respectively. The method was successfully applied to field samples collected from two different areas at Gwangju and Muan. The decline in the resiudue concentrations was best ascribed to a first-order kinetic model with half-lives of 5.7 and 4.6 days. The variation between the patterns was attributed to humidity. Copyright (c) 2015 John Wiley & Sons, Ltd.

Anahtar kelimeler

VALIDATION DIODE-ARRAY DETECTION TANDEM MASS-SPECTROMETRY GRAPES DISSIPATION PESTICIDE-RESIDUES LC-UVD pyraclostrobin perilla leaf interferences SPE-d-SPE combination TIME-OF-FLIGHT STROBILURIN FUNGICIDES GLOBAL UNCERTAINTY AZOXYSTROBIN

Atıf için künye

Farha, W., Rahman, M. M., Hassıbelnaby, A. M. A., Jung, D., Kabir, M. H., Choi, J., Kim, S., Im, S. J., Lee, Y., Shin, H., Kwon, C., Son, Y., Lee, K., & Shim, J. (2015). A combination of solid-phase extraction and dispersive solid-phase extraction effectively reduces the matrix interference in liquid chromatography-ultraviolet detection during pyraclostrobin analysis in perilla leaves. Biomedical Chromatography, 29(12), 1932–1936. https://doi.org/10.1002/bmc.3523

BibTeX 
@article{farha2015-209762,
  author = {Farha, Waziha and Rahman, Md. Musfiqur and Hassıbelnaby, Abdelaty Mostafa Abdelaty and Jung, Da-I. and Kabir, Md. Humayun and Choi, Jeong-Heui and Kim, Sung-Woo and Im, So Jeong and Lee, Young-Jun and Shin, Ho-Chul and Kwon, Chan-Hyeok and Son, Young-Wook and Lee, Kang-Bong and Shim, Jae-Han},
  title = {A combination of solid-phase extraction and dispersive solid-phase extraction effectively reduces the matrix interference in liquid chromatography-ultraviolet detection during pyraclostrobin analysis in perilla leaves},
  journal = {Biomedical Chromatography},
  year = {2015},
  volume = {29},
  number = {12},
  pages = {1932--1936},
  issn = {0269-3879},
  doi = {10.1002/bmc.3523},
  url = {https://akademik.atauni.edu.tr/yayinlar/209762-a-combination-of-solid-phase-extraction-and-dispersive-solid-phase-extraction}
}