Evaluation of Lavandula mairei extract as green inhibitor for mild steel corrosion in 1 M HCl solution. Experimental and theoretical approach

Berrissoul, A.; Ouarhach, A.; Benhiba, F.; Romane, A.; Zarrouk, A.; Guenbour, A.; Dikici, Burak; Dafali, A.

doi:10.1016/j.molliq.2020.113493

Makale Tam Makale Uluslararası 2020

Evaluation of Lavandula mairei extract as green inhibitor for mild steel corrosion in 1 M HCl solution. Experimental and theoretical approach

A. Berrissoul, A. Ouarhach, F. Benhiba, A. Romane, A. Zarrouk, A. Guenbour, Burak Dikici, A. Dafali

Journal of Molecular Liquids Cilt 313 · 01.09.2020

DOI ile aç

Özet

Corrosion inhibition of mild steel sample in hydrochloric acid solution was examined via weight loss and electrochemical measurements, Scanning Electron Microscopy (SEM) and X-ray Photoelectron Spectroscopy (XPS) techniques. The use of Lavandula mairei Humbert extract (LM) as an eco-friendly inhibitor of mild steel (MS) corrosion in 1 M HCl solution has significantly decreased MS corrosion rate. The corrosion inhibition efficiency increased with the increase of LM concentration up to 92% obtained at 303 K for a 0.4 g/ L concentration. The adsorption of LM inhibitor on the mild steel surface followed the Langmuir adsorption isotherm. Anodic Tafel slope digression and continuous CR lessening with the LM extract concentration increase, has validated the limited dissolution of mild steel. Theoretical approaches based on chemical quantum calculations and molecular dynamics simulation clearly explains the mode of adsorption of the majority molecule on the metal surface. (C) 2020 Elsevier B.V. All rights reserved.

Anahtar kelimeler

Surface morphology MASS-SPECTROMETRY CHEMICAL-COMPOSITION ESSENTIAL OILS Monte Carlo simulation Molecular dynamics Impedance spectroscopy CARBON-STEEL Phosphoric acid Theoretical approach Electrochemical techniques Mild steel corrosion Lavandula mairei extract SEM/XPS HYDRAZINE DERIVATIVES

Atıf için künye

Berrissoul, A., Ouarhach, A., Benhiba, F., Romane, A., Zarrouk, A., Guenbour, A., Dikici, B., & Dafali, A. (2020). Evaluation of Lavandula mairei extract as green inhibitor for mild steel corrosion in 1 M HCl solution. Experimental and theoretical approach. Journal of Molecular Liquids, 313. https://doi.org/10.1016/j.molliq.2020.113493

BibTeX

@article{berrissoul2020-196620,
  author = {Berrissoul, A. and Ouarhach, A. and Benhiba, F. and Romane, A. and Zarrouk, A. and Guenbour, A. and Dikici, Burak and Dafali, A.},
  title = {Evaluation of Lavandula mairei extract as green inhibitor for mild steel corrosion in 1 M HCl solution. Experimental and theoretical approach},
  journal = {Journal of Molecular Liquids},
  year = {2020},
  volume = {313},
  issn = {0167-7322},
  doi = {10.1016/j.molliq.2020.113493},
  url = {https://akademik.atauni.edu.tr/yayinlar/196620-evaluation-of-lavandula-mairei-extract-as-green-inhibitor-for-mild-steel}
}