Makale
Tam Makale
Uluslararası
1999
Kinetics and mechanism of aqueous oxidation of H2S by Fe+3
International Journal of Chemical Kinetics
Cilt 31 · Sayı 5 · ss. 331–335 · 01.05.1999
Özet
The reaction kinetics of aqueous oxidation of H2S by Fe+3 is investigated at 25 degrees C by spectrophotometric method. The study conducted at various reactant concentrations and pH revealed that the reaction proceeds according to complex-series reactions involving polysulfides as intermediates. The reaction of each step is first order with respect to Fe+3 and hydrogen sulfide or polysulfide. A mechanism is proposed, involving sulfide and polysulfido radicals. (C) 1999 John Wiley & Sons, Inc.
Atıf için künye
Tekin, T., BOYABAT, N., & BAYRAMOĞLU, M. R. (1999). Kinetics and mechanism of aqueous oxidation of H2S by Fe+3. International Journal of Chemical Kinetics, 31(5), 331–335.
BibTeX
@article{tekin1999-188552,
author = {Tekin, Taner and BOYABAT, Nesrin and BAYRAMOĞLU, MAHMUT RAHİM},
title = {Kinetics and mechanism of aqueous oxidation of H2S by Fe+3},
journal = {International Journal of Chemical Kinetics},
year = {1999},
volume = {31},
number = {5},
pages = {331--335},
issn = {0538-8066},
url = {https://akademik.atauni.edu.tr/yayinlar/188552-kinetics-and-mechanism-of-aqueous-oxidation-of-h2s-by-fe3}
}