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Improvement of carbon dioxide tolerance of PEMFC electrocatalyst by using microwave irradiation technique

Ayşe Bayrakçeken, Lemi Tuerker, Eroglu Inci

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY Cilt 33 · Sayı 24 · ss. 7527–7537 · 01.12.2008
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Özet

The microwave irradiation technique was used to prepare platinum and platinum-ruthenium-based electrocatalysts on Vulcan for PEMFCs. The effects of microwave duration, base concentration and surfactant/precursor ratios on the properties of Pt-based catalysts were investigated. The prepared Pt-based catalysts were characterized by XRD and then PEMFC tests were performed. The particle sizes of the catalysts were ranging between 2 and 6 nm. Platinum-ruthenium-based catalysts were prepared to improve the carbon dioxide tolerance of the PEMFCs. The power losses arising from carbon dioxide in hydrogen feed were decreased by using the prepared PtRu-based catalysts when 30% carbon dioxide including hydrogen was sent to the fuel cell. (c) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

Anahtar kelimeler

COMPONENTS microwave irradiation nanoparticles PARTICLE-SIZE support Electrocatalyst Co catalysts HYDROGEN PEM fuel cell Carbon black POLYOL SYNTHESIS FUEL-CELLS

Atıf için künye

Bayrakçeken, A., Tuerker, L., & Inci, E. (2008). Improvement of carbon dioxide tolerance of PEMFC electrocatalyst by using microwave irradiation technique. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 33(24), 7527–7537. https://doi.org/10.1016/j.ijhydene.2008.09.069

BibTeX
@article{bayrakceken2008-187530,
  author = {Bayrakçeken, Ayşe and Tuerker, Lemi and Inci, Eroglu},
  title = {Improvement of carbon dioxide tolerance of PEMFC electrocatalyst by using microwave irradiation technique},
  journal = {INTERNATIONAL JOURNAL OF HYDROGEN ENERGY},
  year = {2008},
  volume = {33},
  number = {24},
  pages = {7527--7537},
  issn = {0360-3199},
  doi = {10.1016/j.ijhydene.2008.09.069},
  url = {https://akademik.atauni.edu.tr/yayinlar/187530-improvement-of-carbon-dioxide-tolerance-of-pemfc-electrocatalyst-by-using}
}