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REMOVAL OF COD AND COLOR FROM REACTIVE RED 45 AZO DYE WASTEWATER USING FENTON AND FENTON-LIKE OXIDATION PROCESSES: KINETIC STUDIES

Serkan Bayar, M. Erdogan

APPLIED ECOLOGY AND ENVIRONMENTAL RESEARCH Cilt 17 · Sayı 2 · ss. 1517–1529 · 01.01.2019
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Özet

The present study dealt with the removal of Reactive Red 45 (RR45) azo dye material through Fenton and Fenton-like oxidation processes. The effects of pH, Fe2+ and Fe3+ dosages, hydrogen peroxide (H2O2), concentration of colorant and temperature were evaluated. Removal of the colorant RR45 was monitored by considering color and Chemical Oxygen Demand (COD). Results showed that Fenton process is more efficient than Fenton-like processes in terms of color and COD removal efficiency. A removal efficiency of 91.1% of COD and 99.90% of color was obtained under optimum experimental conditions where initial solution pH was 3, the concentration of RR45 colorant was 200 mg L-1, rates of Fe2+ and H2O2 were 75 mg L-1 and 400 mg L-1, respectively, reaction temperature was 50 degrees C and experiment time was 30 min. In addition, the first order, second order and Behnajady-Modirshahla-Ghanbery (BMG) models were applied and the best results were obtained by BMG model.

Anahtar kelimeler

Efficiency toxicity DEGRADATION AQUEOUS-SOLUTION H2O2 REAGENT COLORANT Hydroxyl radical Fenton reaction kinetic modelling DECOLORIZATION KINETICS

Atıf için künye

Bayar, S., & Erdogan, M. (2019). REMOVAL OF COD AND COLOR FROM REACTIVE RED 45 AZO DYE WASTEWATER USING FENTON AND FENTON-LIKE OXIDATION PROCESSES: KINETIC STUDIES. APPLIED ECOLOGY AND ENVIRONMENTAL RESEARCH, 17(2), 1517–1529. https://doi.org/10.15666/aeer/1702_15171529

BibTeX
@article{bayar2019-180462,
  author = {Bayar, Serkan and Erdogan, M.},
  title = {REMOVAL OF COD AND COLOR FROM REACTIVE RED 45 AZO DYE WASTEWATER USING FENTON AND FENTON-LIKE OXIDATION PROCESSES: KINETIC STUDIES},
  journal = {APPLIED ECOLOGY AND ENVIRONMENTAL RESEARCH},
  year = {2019},
  volume = {17},
  number = {2},
  pages = {1517--1529},
  issn = {1589-1623},
  doi = {10.15666/aeer/1702_15171529},
  url = {https://akademik.atauni.edu.tr/yayinlar/180462-removal-of-cod-and-color-from-reactive-red-45-azo-dye-wastewater-using-fenton}
}