REACTIONS OF BENZOCYCLOHEPTENES WITH DIENOPHILES

Adam, W; Balcı, Metin; Ceylan, Zeynep; Hınz, R.F.

doi:10.1002/cber.19911240222

Makale Tam Makale Uluslararası 1991

REACTIONS OF BENZOCYCLOHEPTENES WITH DIENOPHILES

W Adam, Metin Balcı, Zeynep Ceylan, R.F. Hınz

CHEMISCHE BERICHTE Cilt 124 · Sayı 2 · ss. 383–386 · 01.02.1991

DOI ile aç

Özet

The Diels-Alder reactions of 5H-benzocycloheptene (1) with tetracyanoethylene (TCNE) afforded the [2 + 2] and [4 + 2] cycloadducts 7, 8, and 10 and the benzodicyanoheptafulvalene 9. The norcaradiene product 10 was synthesized independently by cycloaddition of TCNE to 7H-benzocycloheptene (3). The addition of 4-methyl-1,2,4-triazoline-3,5-dione (MTAD) to 3 gave bis-urazole 13, which was formed by ene reaction followed by [4 + 2] cycloaddition. The spirocycloheptatriene 15 gave with 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) the bisurazole 16.

Atıf için künye

Adam, W., Balcı, M., Ceylan, Z., & Hınz, R. (1991). REACTIONS OF BENZOCYCLOHEPTENES WITH DIENOPHILES. CHEMISCHE BERICHTE, 124(2), 383–386. https://doi.org/10.1002/cber.19911240222

BibTeX

@article{adam1991-178807,
  author = {Adam, W and Balcı, Metin and Ceylan, Zeynep and Hınz, R.F.},
  title = {REACTIONS OF BENZOCYCLOHEPTENES WITH DIENOPHILES},
  journal = {CHEMISCHE BERICHTE},
  year = {1991},
  volume = {124},
  number = {2},
  pages = {383--386},
  issn = {0009-2940},
  doi = {10.1002/cber.19911240222},
  url = {https://akademik.atauni.edu.tr/yayinlar/178807-reactions-of-benzocycloheptenes-with-dienophiles}
}