Makale
Tam Makale
Uluslararası
1996
An unusual zinc-promoted reductive retro-Wagner-Meerwein rearrangement
TURKISH JOURNAL OF CHEMISTRY
Cilt 20 · Sayı 4 · ss. 335–340 · 01.01.1996
Özet
Bromination and dehydrobromination of exocyclic olefin 8 resulted in the formation of bromomethylene compound 9 and Wagner-Meerwein rearrangement product 10. The dehydrobromination of 10 with potassium tert-butoxide provided the corresponding bromomethyl compound 11 in high yield. Reaction of 11 with Zn-Cu couple in methanol afforded the methyl derivative 12 and the parent olefin 8. The unusual formation mechanism of 8 has been discussed in term of a reductive retro-Wagner-Meerwein rearrangement.
Atıf için künye
Taşkesenligil, Y., & BALCI, M. (1996). An unusual zinc-promoted reductive retro-Wagner-Meerwein rearrangement. TURKISH JOURNAL OF CHEMISTRY, 20(4), 335–340. http://journals.tubitak.gov.tr/chem/abstract.htm?id=638
BibTeX
@article{taskesenligil1996-153037,
author = {Taşkesenligil, Yavuz and BALCI, Metin},
title = {An unusual zinc-promoted reductive retro-Wagner-Meerwein rearrangement},
journal = {TURKISH JOURNAL OF CHEMISTRY},
year = {1996},
volume = {20},
number = {4},
pages = {335--340},
issn = {1010-7614},
url = {https://akademik.atauni.edu.tr/yayinlar/153037-an-unusual-zinc-promoted-reductive-retro-wagner-meerwein-rearrangement}
}