Hydrothermally Synthesized CoS₂ Nanostructures for Efficient and Recyclable Adsorptive Removal of Methylene Blue Contributing to Water Depollution

The powder of cobalt disulfide (CoS2) was successfully prepared using the hydrothermal method at the temperatures of 150, 180, and 210 degrees C for 24 h. The series of characterization techniques, including SEM, EDX, XRD, and FTIR, confirmed the formation of pure CoS2 with a cubic crystal structure and an average crystallite size of about 14 nm, present in the form of spherical nanoparticles (NPs), whose diameters increased with increasing of the temperature. The adsorption activity of the CoS2 NPs was evaluated by using methylene blue (MB) dye. The study showed that all samples of CoS2 NPs are efficient adsorbents for MB under alkaline conditions (pH = 12). The kinetic study conducted on the most effective adsorbent obtained at 150 degrees C, representative of the synthesized CoS2 NPs, demonstrated that the pseudo-second-order is the kinetic model that describes the adsorption phenomenon. The analysis of the adsorption isotherms revealed that the process adopts the Freundlich model with a high correlation coefficient (R 2 = 0.99), indicating multilayer adsorption on a heterogeneous surface. The adsorption capacity increased with the temperature from 128.20 mg/g at 298 K to 222.22 mg<middle dot>g-1 at 318 K, suggesting an endothermic process. The recyclability tests demonstrated that CoS2 NPs are stable and reusable adsorbents, showing a slight decrease in the MB removal efficiency, approximately 4%, after six successive reuses.

Journal

ACS OMEGA

Year

2025

Volume

10

Issue

51

Pages

62895-62905

ISSN

2470-1343

DOI

10.1021/acsomega.5c08568

WoS UID

WOS:001642248900001